The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Most of what has been said of the mutual solution of liquids is also
true of the solution of solids, but the latter may be divided into two
very distinct classes, colloids and crystalloids (which, however, shade
off into each other). The colloid or gluey bodies are mostly miscible in
any proportion with liquids in which they dissolve, and there is no such
thing as a definite point of saturation. There are however some which
form _jellies_ which have great analogy to the partially miscible
liquids; there is a mutual solubility, a portion of the solid dissolving
to a liquid solution, while the remainder of the liquid dissolves in the
solid, increasing its volume, but still retaining the characteristics of
the solid state. As the temperature is raised, this mutual solubility
generally increases, till at a given point the jelly melts, and complete
solution takes place, as in the case of partially miscible liquids.
These phenomena are of prime importance in the theory of tanning, but
their further consideration must be deferred till a few words have been
said about the crystalloids. These are characterised by regular
crystalline form, indicating that the attractive forces of their
molecules are exerted in definite directions, giving them a tendency to
attach themselves together in definite geometrical arrangements. They
dissolve in themselves no part of the solvent, but are dissolved by it
till an equilibrium is reached in which the tendency of further
particles of the solid to pass into the solvent is balanced by that of
those already dissolved to attach themselves to the remaining solid, or
“crystallise out.” Such a solution is “saturated” with respect to the
solid residue, but the word has no meaning unless solid crystals are
present, and where a body has, as sometimes happens, more than one
crystalline form, a solution may be saturated with regard to one of
them, and more or less than saturated with regard to another. In
“supersaturated” solutions, crystallisation is at once started by the
addition of a “seed” crystal of the proper form.
If a crystalloid substance, such, for instance, as copper sulphate, be
placed in a solvent (e. g. water), the dissolved salt will gradually
spread itself through the whole body of the solvent, though in the
complete absence of currents in the liquid, the motion is extremely
slow, and years may be taken for the diffusion to rise through a few
feet. In many cases salts diffuse through aqueous jellies at the same
speed as they would through still water. Colloid substances on the other
hand have little or no power of diffusion and mostly cannot pass through
jellies at all. This is the reason why tannage with mineral salts is so
much more rapid than with vegetable tannins which are of colloidal
character, and diffuse through the gelatinous fibres of the hide with
extreme slowness.
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