The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The peculiarities which were shown by the hide pieces on removal from
the water were maintained throughout the tanning, which was conducted in
imitation of the German method, the hide being swollen and coloured
through in weak birch-bark liquors, made with distilled water and
acidified in each case with equal quantities of lactic acid, and finally
laid away, till tanned, in a mixture of oak bark and valonia. No. 6,
from magnesium sulphate, was the best; then No. 2; No. 3 was less good,
but all the pieces from 1 to 6 were firm, close and of good substance
and texture, No. 1 having swelled well in the sour liquor. On the other
hand, 7 and 8 scarcely swelled in liquor, but remained flat throughout,
and were looser, thinner and of finer fibre. From this experiment it is
clear that while sulphates and carbonates exert a favourable influence
on plumping, chlorides do the reverse, as they themselves not only do
not plump, but they place the hides in an unfavourable condition for the
plumping action of acids in the liquors. These experiments are quite
borne out by the writer’s experience in practice. The water at the
Lowlights Tannery, which in dry weather was mostly obtained from beds of
what was originally sea-sand, and which consequently contained a very
abnormal proportion of chlorides (up to 68 pts. NaCl per 100,000),
required special and very careful management to make thick leather,
notwithstanding the fact that it contained a considerable quantity of
calcium and magnesium sulphates. These facts also indicate the
importance of the thorough removal of salt from hides intended for
sole-leather. Plumping is not a desirable thing in leather intended for
dressing purposes, and it is possible that the use of a small percentage
of salt in the liquors or wash waters might in some cases enable bating
to be dispensed with. Like a bate, salt would dissolve a small
proportion of hide substance (see p. 65). There is no practicable means
of removing chlorides from water, but Eitner suggests the addition of a
small quantity of sulphuric acid to water containing much temporary
hardness (bicarbonates), in order to convert it into permanent hardness
(sulphates), which, as stated above, plumps better. The amount required
may be calculated from an acidimetric determination of temporary
hardness (see L.I.L.B., p. 19). A simple but not very accurate guide, is
to add enough acid to purple, but not to redden litmus paper even after
moving the latter about in the water for some minutes. In practice the
acid must of course be very thoroughly mixed with the water by stirring
and plunging. It must be borne in mind that Eitner’s experiment was on
sweated hides, and that with limed hide, which is kept plump by the
dissolved lime retained in the hide, different results as regards
carbonic acid and bicarbonates would be obtained. Both these would
convert the lime in the hide into chalk, which is insoluble and inert,
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