The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The use of dilute acids for softening has much to recommend it, their
power of causing the fibre to swell and absorb water being quite equal
to that of the alkalies, while few, if any, putrefactive bacteria can
thrive in an acid liquid. Very dilute sulphuric acid has been used with
success to dissolve the alkaline “plaster” of East India kips (p. 39).
It has considerable disinfectant power (p. 23), but its action on the
hide-fibre is undesirably strong.
Sulphurous acid is much more suitable. Its use for this purpose was
patented by Maynard, along with a number of other possible uses, but the
patent has now lapsed, and he does not seem to have succeeded in
introducing it into practice. Experiments at the Yorkshire College, and
also at a tannery on a manufacturing scale, have shown that the method
is capable of excellent results. The hides are soaked for 24-48 hours in
a solution of sulphurous acid containing about 2 per cent. of SO₂ (for
manufacture, compare p. 24; for testing, L.I.L.B., pp. 16, 37), and are
then transferred to water, where they swell freely to their full
thickness. They may be either limed at once, or first neutralised with
dilute caustic soda, ammonia, or sulphide of sodium, which, for dressing
leather, is perhaps desirable. No putrefaction takes place, even if they
are retained for a considerable time in water, and the acid has little
or no solvent effect on the hide-fibre, the strength of which is well
preserved. The liming, however, must either be conducted with the aid of
sodium sulphide or in old limes, since the sterile condition of the
hides renders liming in fresh lime very slow (cp. p. 137). For
experimental purposes a ¹⁄₂ per cent. solution of Boakes’
“metabisulphite of soda” may be used, to which ¹⁄₄ per cent. of
concentrated sulphuric acid previously diluted with water is gradually
added during the soaking, the hides being first withdrawn. For permanent
work it will be found much cheaper to manufacture the acid on the spot
by burning sulphur.
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