The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
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The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The use of solutions of caustic soda (1 part per 1000), or of sodium
sulphide (1¹⁄₂-3 parts per 1000) as suggested by Eitner, seems at
present likely to supersede all other methods of softening from their
simplicity and safety. Twenty-four to forty-eight hours in either of
these solutions, which may if necessary be followed by a short soak in
plain water, seem sufficient to soften either kips or hides. Experiments
at the Yorkshire College have shown that solutions of this strength have
little or no solvent action on the hide-fibre, but promote its swelling
in water so effectively that no mechanical softening is needed (though a
slight drumming is advantageous), while putrefaction is almost entirely
prevented, so that the solution may be repeatedly used if kept up to its
original strength, which is easily determined with standard acid and
phenolphthalein (see L.I.L.B., p. 17). Neither caustic soda nor sodium
sulphide have any injurious effect on liming, though it may prove
somewhat slower than with the older methods, where the epidermis was
partially destroyed by the action of putrid ferments. The dilute
solutions used are not only less injurious to the hide than those of
greater strength, but they are also more effective in softening. Eitner
(Gerber, 1899, p. 584) states that when using a solution of caustic soda
of 1 part in 1000 strength, the time required to soften some hides was
only two days, as against three days for a sodium sulphide liquor, and
four days for pure water, and that with the soda solution only about 0·6
per cent of the hide-substance of the skin was dissolved out, whilst
when sodium sulphide was used it was 0·7 per cent., and with pure water
alone no less than 1·9 per cent. was lost by solution.
The use of moderately warm water (40° C.) in a drum is quite successful
in rapidly softening sound hides after they have previously been soaked
for some days in cold water; but if they are tainted in the cure, it is
very apt to intensify the mischief. Hides which have partially putrefied
internally, or which have been exposed to a hot sun while the interior
is still moist, are very apt to appear sound while dry, but to blister
or go to pieces from the destruction of the fibres as soon as they are
limed, and this in spite of even the most careful treatment. For tainted
hides, caustic soda is probably preferable to sodium sulphide.
Public-domain text, read in full here on John Shaqi.
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