History, Modern -- 19th century; Nineteenth century
chlorine; and each liberated atom of hydrogen unites with a liberated
atom of chlorine, forming a compound, hydrogen chloride, which equally
consists of a molecule, or double atom. Thus two cubic inches of
hydrogen chloride consist of a definite number of molecules, equal
in number to those contained in a cubic inch of hydrogen, plus those
contained in a cubic inch of chlorine. The case is precisely similar,
if other compounds of gases be considered.
Berzelius was at first inclined to adopt this theory, and indeed went
so far as to change many of his atomic weights to make them fit it.
But later he somewhat withdrew from his position, for it appeared to
him that it was hazardous to extend to liquids and solids a theory
which could be held only of gases. Avogadro’s suggestion, therefore,
rested in abeyance until the publication, in 1858, by Cannizzaro, now
professor of chemistry in Rome, of an essay in which all the arguments
in favor of the hypothesis were collected and stated in a masterly
manner. It will be advisable to revert to this hypothesis at a later
point, and to consider other guides for the determination of atomic
weights.
In 1819, Dulong (1785–1838), director of the Ecole Polytechnique at
Paris, and Petit (1791–1820), professor of physics there, made the
discovery that equal amounts of heat are required to raise equally the
temperature of solid and liquid elements, provided quantities are taken
proportional to their atomic weights. Thus, to raise the temperature of
56 grammes of iron through one degree requires approximately the same
amount of heat as is required to raise through one degree 32 grammes of
sulphur, 63.5 grammes of copper, and so on; these numbers representing
the atomic weights of the elements named. In other words, _equal
numbers of atoms have equal capacity for heat_. The number of heat
units, or calories (one calory is the amount of heat required to raise
the temperature of 1 gramme of water through 1° C.), which is necessary
to raise the atomic weight expressed in grammes of any solid or liquid
element through 1° C. is approximately 6.2; it varies between 5.7 and
6.6 in actual part. This affords a means of determining the true value
of the atomic weight of an element, as the following example will show:
The analysis of the only compound of zinc and chlorine shows that it
contains 47.49 per cent. of zinc and 52.16 per cent. of chlorine. Now
one grain of hydrogen combines with 35.5 grains of chlorine to form
36.5 grains of hydrogen chloride; and, as already remarked, one volume
of hydrogen and one volume of chlorine combine, forming two volumes of
hydrogen chloride. Applying Avogadro’s hypothesis, one molecule of
hydrogen and one molecule of chlorine react to yield two molecules of
hydrogen chloride; and as each molecule is supposed to consist in this
case of two atoms, hydrogen chloride consists of one atom of each of
its constituent elements. The amount of that element, therefore, which
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