The progress of the marbling art, from technical scientific principles : $b with a supplement on the decoration of book edgesHalfer, Josef
Science
The progress of the marbling art, from technical scientific principles : $b with a supplement on the decoration of book edges
Halfer, Josef
Marbled papers; Marbling (Bookbinding)
The preparation of carrageen size is confined to one ever recurring
manipulation, which must be repeated every eight days, if an always good
and useful size is desired; the expenses are very trifling, a few cents
for the best kind of carrageen. If bought in larger quantities the
expenses for carrageen can still be reduced. For the preparation of the
size take a new pot, which must always be used for this purpose
exclusively, pour in six quarts of water, which quantity is sufficient
to twice or three times fill the usual marbling trough, add 2-1/2 ounces
of Carrageen moss and boil until the water bubbles up several times. A
longer boiling is injurious because the mucilage becomes flaky and
muddy. 2/5 of an ounce of Carrageen to one quart of water is fully
sufficient to produce a consistent size, provided that only the best
Carrageen is used.
Soft water or rain water was formerly used exclusively for preparing the
size, as by using it a greater durability was obtained.
During my researches, regarding the durability of the varieties of
sizes, I found means by which the influence of hard water on the ground
can be suspended, so that spring and pump water can now be used without
any danger.
Every kind of hard water contains mineral salts, spring water especially
containing lime in smaller or larger quantities. This can be seen, when
the soap, which is used in such water, curdles, because of the
ingredients of soap stearine palmitic or fatty acids of sodium or
potassium, form a combination with the lime, to carbonate of lime, and
the potash soap is converted into an insoluble lime soap. If we add to
hard water a quantity of sodium or potassium, the carbonate of lime is
precipitated as a white or yellowish powder, according to the quantity
of iron contained in the water, and a soft water remains.
The sun produces on a great scale in nature, what the chemist achieves
on a smaller scale by evaporation or precipitation and cooling of steam,
a water free of all mineral salts, which we call distilled water. Rain
water is the same, but the flowing water derived from a river already
contains mineral salts in greater or smaller quantities, which are
brought into it by different springs and substances. The water gained by
precipitations is considered soft. Carbonates of sodium or potassium are
strong bases, exactly the opposite of acids, and they therefore prohibit
the oxidation in plant mucilages. This chemical reaction against the
formation of acids I used for the purpose of prohibiting a deterioration
of the size by adding sodium, in which I was thoroughly successful, as
it can easily be preserved in a cool place for even eight or ten days.
Two obstacles offered themselves, which I have overcome after a tireless
and thorough investigation, first the strongly alkaline property of the
size which was generated by the added carbonate of sodium and second the
fermentation of lactic acid which occurred notwithstanding the sodium
and made the size useless.
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