The Propaganda for Reform in Proprietary Medicines, Vol. 2 of 2Council on Pharmacy and Chemistry (American Medical Association)
Science
The Propaganda for Reform in Proprietary Medicines, Vol. 2 of 2
Council on Pharmacy and Chemistry (American Medical Association)
Patent medicines
“B. OLEUM IODINE: Iodine soluble in mineral oil 5 and 10% for
Nasal, Pharyngeal, Laryngeal, Bronchial, Rectal, etc., and all
meucoid affections and abnormal conditions of the mucous membrane.”
A sample of B. Oleum Iodine was submitted by the manufacturer and
examined. The label on the bottle states that it is 5 per cent. B.
Oleum Iodine in mineral oil. This sample has the characteristics of
a solution of iodin in liquid petrolatum. It is oily and has the
characteristic violet color.
_Ammonia_: B. Oleum Iodine, since it is presumed to be a solution of B.
Iodine, was examined for ammonium compounds. A small quantity was mixed
with an equal volume of strong sodium hydroxid solution and heated. No
ammonia was evolved. A few crystals of ammonium chlorid were added to
a little of B. Oleum Iodine and treated as above. Ammonia was readily
detected.
_Iodine_: 5.255 gm. B. Oleum Iodine was dissolved in chloroform and
placed in a separator. A solution of potassium iodid was added and the
iodin titrated with a tenth-normal sodium thiosulphate solution. It
required 3.5 c.c. indicating 0.85 per cent. iodin.
The conclusion is that B. Oleum Iodine is a simple solution of iodin in
liquid petrolatum to the extent of 0.85 per cent. and not 5 per cent.
as claimed. Furthermore, it is not a solution of B. Iodine since no
ammonium compound is present.
The preceding report was sent to the B. Iodine Chemical Company. The
following reply was received:
Your letter of the 21st inst., received and contents noted and
cannot quite agree with your report.
Reasons why: NH₄I, a Nitro Hydrate Iodide; NH₄I₂, a Nitro Hydrate
Iodate; and NH₄I₂I₂, Per Iodide, a molecular compound, which I
claim, they all being of a NH group, so what can be the objection
of Nitrogen Hydrate of Iodine? Of course when your chemist, with
the aid of heat, drove off all the Iodine, he naturally brought it
back to a NH₄I. There’s where he gets the A.M.. I claim a molecular
compound.
The Oil of Iodine I sent you by mistake was a 1 per cent. and not
a 5 per cent. as marked. I claim it is made from the resublimed
Iodine in mineral oil and not the B. Iodine. I claim a 5 per cent.
has heretofore never been accomplished, so I therefore can claim
something new.
Tr. Iodine contains Alcohol and Potash as a base, the alcohol a
dehydrater and Potash an escharotic, and all other soluble Iodines
like the tincture have a metallic base. Mine has not. My iodine is
compatible almost with all the salts, alkaloids, tannates, and even
the metals. You can’t say that for the tincture or the others. Now
why should mine not be superior to others?
Preparations as yet are not on the market and a few pamphlets were
printed to meet with the requirements of your rulings and approval
and shall be corrected if we only can agree on a proper name as you
may suggest.
Public-domain text, read in full here on John Shaqi.
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