The Puering, Bating & Drenching of SkinsWood, Joseph Turney
Science
The Puering, Bating & Drenching of Skins
Wood, Joseph Turney
Leather
A similar process, by the same author (_U.S. Pat._ 798,293), is
described by Dr. Allen Rogers[144] in which 5 per cent. of glucose
syrup and 10 per cent. of sulphur, computed on the weight of the skins,
is fermented with yeast for twenty-four hours, after which it is used
as a bate. From a chemical point of view, it is difficult to express
the reactions taking place.
[144] J.S.C.I. 1906, p. 103.
When the bath is first prepared, it is neutral in reaction, but, after
standing, gradually assumes a slight acid reaction. On introducing the
skins, it becomes alkaline, owing to diffusion of the lime. After a
short time, it becomes neutral again, and remains thus until the skins
are in a perfect condition, when a slight acid reaction is observed.
These changes are caused by the fermentation of the glucose, carbon
dioxide and alcohol being generated. Owing to the presence of sulphur,
a quantity of hydrogen sulphide is produced, which, in its nascent
condition, combines with the alcohol to form mercaptans, which in their
turn are slowly oxidized to thioacids. These mercaptans and thioacids,
being of weak acid character, act in conjunction with any excess of
hydrogen sulphide upon the lime, converting it into soluble compounds,
which are readily removed by diffusion.
*Lederer, L.* (_French Pat. No._ 404,926 _of_ 1909).--Method of
Preparing a Substitute for Animal Excrement (dog dung) in Puering
Skins for Glacé Leather. In this process a mixture of 10 parts finely
powdered bone meal, and 1 part of crushed lupin seeds or beans is
formed into a paste with water and allowed to undergo spontaneous
fermentation from 3–4 weeks. The mixture is said to form a perfect
culture medium for the micro-organisms indispensable in bating. The
removal of the lime is facilitated by the addition of 2 per cent. of
fat, 0·75 per cent. sodium polysulphide and 1-1/2 per cent. common salt
reckoned on the weight of the bone meal.
In this patent the researches of Wood, Andreasch and Eitner are
referred to, and also Benker’s process of bating with Peruvian guano to
which soda has been added.
Public-domain text, read in full here on John Shaqi.
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