The Puering, Bating & Drenching of SkinsWood, Joseph Turney
Science
The Puering, Bating & Drenching of Skins
Wood, Joseph Turney
Leather
*Amend, Otto Paul*, New York (_U.S. Pat._ 763,347, 1904; _Eng. Pat._
18,514 _and_ 18,514A, 1904).--Improved Process for Bating and Puering
Skins, and Improvements relating to the Bating, De-acidifying and
Oxidizing of Hides and Skins.
The skins are treated with a solution of an ammoniacal salt, small
quantities of an acid such as hydrochloric acid being added at
intervals, so as to reform the salts. Pickled skins are de-acidified
and oxidized by treatment in a neutral or slightly alkaline solution of
a nitrite of an alkali or alkaline earth such as sodium nitrite.
*Nowak, O. H.*, Chicago (_French Pat._ 360,854, 1905; _Eng. Pat._
26,771, 1905).--Substance for Treating Hides and Process for Making
same. This is the “dermiforma” described in Chapter VII. Although
bacterial action is used to prepare the bate, the essential action is
an acid one, and, as we have said, resembles the drench.
*Norris, W. M.*, New Jersey (_U.S. Pat._ 840,794, 1907; _Eng. Pat._
29,661, 1906).--Improved Process of Treating Hides and Skins. In this
process the skins are subjected to treatment with a dilute solution
of hyposulphite of soda, which is said to “set” the gelatinous fibres
of the skin. The deliming is completed with hydrochloric acid in the
presence of salt.
*Boehringer Sohn, C. H.* (_Eng. Pat._ 3,140, 1911) Proposes to use in
place of the free organic acid, in this case lactic, the sodium salt,
and then to add slowly the amount of hydrochloric or sulphuric acid
requisite for deliming. The mineral acid combines with the sodium salt,
liberating an equivalent amount of the weaker organic acid, which then
acts upon the lime in the skins. For deliming 100 kilos. of pelt, 0·25
kilo. of sodium lactate (50 per cent.) and 0·56 kilo. hydrochloric acid
(20° Bé.) are used.
The advantage of the method is that a considerable saving is effected
in comparison to the quantity of the free organic acid which would be
required. In the above example 1 kilo. of lactic acid (43 per cent.)
would be required to neutralize a corresponding amount of lime.
In addition to these deliming processes, there are a number of bates in
which various nutritive media are allowed to ferment naturally, without
the addition of any specific bacteria. Among these may be mentioned:--
*Dr. Nördlinger’s Bate*, in which a paste of potatoes is allowed to
ferment at 30°–37° C. for several days; it is then dried at 40°–50° C.,
and used in the same way as dog dung.
*H. E. Simons’, Phosphorbutyralin*, consists of the beetroot residues
in sugar manufacture which have undergone an acid fermentation, and
contain butyrates and phosphates of ammonia.
*Oakes* (_US. Pat._ 798,070, 1905; _Eng. Pat._ 24,488, 1905).--In this
patent an albuminous body, such as casein is allowed to putrefy, at a
temperature of 100° F., for several days; an equal weight of flowers
of sulphur is then added, and the mixture used as a bate or puer. The
sulphur is said to play an essential part in the bate.
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