The Puering, Bating & Drenching of SkinsWood, Joseph Turney
Science
The Puering, Bating & Drenching of Skins
Wood, Joseph Turney
Leather
The potential at the neutral point, using an auxiliary electrode
filled with N/1 potassium chloride, was 0·69 volts. Potentials below
this point, therefore, indicate an acid reaction, and, conversely,
potentials above 0·69 volts indicate an alkaline reaction. The
apparatus is thus very useful in following the course of the bating
process. The initial potential also enables the hydrion concentration
of the bate liquor to be determined directly (see Chapter III.).
It was found that during the bating of a pack of skins the hydrion
concentration of the liquor diminished from 10^{-5·2} to 10^{-7·4}
normal.
Such acidities as are found by this method, e.g. 7–8 c.c. N/10 acid per
100 c.c., are too great if made up by taking a solution of the free
acids. The ionization must be almost entirely repressed by the presence
of sufficient neutral salts of the same acids in the bating liquid, in
order to obtain a similar result to the puer.
The table opposite gives the values found for a series of puer liquors,
made with dog manure from hunting-kennels.
The reaction of puer liquors (expressed in c.c. of N/1 alkali or acid
per 1000 c.c. of bate), in a series in which the washed goods were run
for one hour in old puer, out of which goods had been taken, and then
transferred to a freshly-made puer, was as follows:--
----------+----------------+--------------
Bate | Before Goods | After Goods
----------+----------------+--------------
Old puer | Neutral | 28 c.c. acid
Fresh | 10 c.c. alkali | Neutral
Old puer | Neutral | 40 c.c. acid
Fresh | 11 c.c. alkali | Neutral
----------+----------------+--------------
These figures were obtained by the ordinary colorimetric method
described on p. 32.
Adding together the alkalinity of the bate run away, and the acidity of
the new bate which is neutralized, the total for 1 and 2 = 38 c.c. N/1
acid, and for 3 and 4, 51 c.c. N/1 acid.
Multiplying by 810 (volume of bate less volume of dry skin), we find
that the skins have neutralized 30·78 and 41·31 litres N/1 acid
respectively. Since one litre of N/1 acid will neutralize 28 grm. of
lime, it follows that the lime removed by the bate was in one case
862 grm., in the other case 1157 grm.
The 500 kilos, of wet washed grains introduced into the paddle contain
approximately 0·5 per cent. of lime CaO, equivalent to 2500 grm.
altogether. As will be seen from the figures given in table, p. 35, the
free acids present in the fresh bate are only capable of neutralizing
10 × 810 c.c. of normal alkali, and this is equivalent to 225 grm. of
CaO, or 9 per cent. of the total lime.[30]
[30] Eitner, Der Gerber, 566, p. 77, states that little or no
neutralization of lime by acids or acid salts takes place in the bate.
Public-domain text, read in full here on John Shaqi.
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