The Puering, Bating & Drenching of Skins — John Shaqi
The Puering, Bating & Drenching of SkinsWood, Joseph Turney
Science
The Puering, Bating & Drenching of Skins
Wood, Joseph Turney
Leather
For the absorption phenomena which occur, the following relation holds
good: When a substance in solution diminishes the surface tension at
the dividing surface, its concentration is increased; it is absorbed.
When a substance in solution increases the surface tension at the
dividing surface, its concentration is diminished.
In the system water-hide substance the researches of Wiedemann and
Lüdkeing have shown that swelling is accompanied by evolution of
heat. Since a rise of temperature is favourable to a system formed by
absorption of heat, it therefore hinders swelling and vice versa. This
is confirmed by practical experience, and most bating operations are
conducted at temperatures between 35° and 40° C.
With regard to the influence of pressure on swelling, a similar law
holds good as for temperature, which may be expressed as follows.
When a chemical system is compressed at constant temperature, its
equilibrium is shifted in that direction by which the reaction is
accompanied by diminution of volume. Quincke, however, has shown
what appears to be a paradox, namely, that swelling is accompanied
by diminution of volume, i.e. the swelling substance, plus the water
taken up, occupies a smaller space than the sum of the two constituents
taken together; therefore, an increase of pressure must be favourable
to swelling, and conversely a diminution of pressure is favourable to
“falling.”
We must clearly bear in mind that in all cases of swelling, it is the
entry of water into the system which is the cause of the swelling, and
since puering is a process which acts in a contrary direction, i.e. the
skin falls, this means that water is expelled from the system, skin
plus water. By direct determination, from 3 to 8 per cent. of water is
expelled during puering. Calculations made from density determinations
are masked by the fact, above referred to, that the density of the skin
changes during puering.
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