The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
Nitromuriate of platina produced no precipitate, however concentrated
the water might be. [p023]
The results of the previous experiments indicate the presence of
Soda, Lime in small proportion,
Muriatic acid, No magnesia,
Sulphuric acid, No iron,
Carbonic acid, No potash.
A. To ascertain the proportion of sulphuric acid, sixteen ounces
by measure, previously saturated by acetic acid, were treated with
muriate of barytes; the precipitate, washed and dried, weighed
one grain; this indicates, in the imperial gallon, 3.2 grains of
sulphuric acid, equivalent to 5.8 sulphate of soda, dry, or 13 grains
crystallized.
B. For the muriatic acid; nitrate of silver, added to sixteen ounces
of the water boiled, and the alkali previously saturated, gave a
precipitate weighing 2.8 grains; reduced to the proportion in the
imperial gallon, this amounts to 26.9 grains chloride of silver,
equivalent to 11 grains chloride of sodium (muriate of soda.)
C. The crystalline pellicle separated from a pint of sixteen ounces,
on boiling, weighed 0.2 grains.
This was carbonate of lime; but in the water the lime would be
combined with muriatic acid, forming 0.22; or, in the imperial
gallon, 2.1 dry chloride, or 3.75 crystallized muriate of lime.
D. The precipitate formed on boiling with muriate of lime, weighed
from the pint, 3.6 grains; from the imperial gallon, 34.6 grains;
showing the water to contain in that quantity a carbonated alkali
equivalent to 53 grains of dry, or 59.5 crystallized bi-carbonate of
soda.
E. Muriate of barytes, added to the water left on evaporating sixteen
ounces to two, gave a precipitate weighing 8.2 grains; deducting one
grain for sulphate of barytes, as found in experiment A, we have 7.2
carbonate of barytes; this indicates in the gallon 53 grains of dry,
and 59.5 of crystallized carbonate of soda, as in the last experiment.
Lastly, a pint of sixteen ounces of the water, evaporated to dryness,
furnished in three trials of saline residuum, weighed after short
exposure to a dull red heat, six grains, or 57.6 from [p024] the
imperial gallon. Now we have seen that this would consist of
5.8 Dry sulphate of soda (exp. A).
11. Chloride of sodium ( — B).
1.9 Carbonate of lime ( — C).
----
18.7
38.9
----
57.6
The remainder, 38.9, having been converted by the heat into
proto-carbonate of soda, is equivalent to 54.5 dry, 61 grains
crystallized bi-carbonate, agreeing nearly with the quantities found
from experiments D and E.
Following, as I do, that doctrine which supposes the bases to be
distributed among the acids in a mineral water in the combinations
which possess the greatest solubility, we must suppose the lime to be
in the state of muriate; we shall then have to diminish the muriate,
and increase the carbonate of soda: so that on this view, the saline
constituents of an imperial gallon, in the state in which they exist
in the water, are,—
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