The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
3. An experiment was then instituted, in which the effect of excess
of chlorine, upon a solution of carbonate of soda of the same
strength as the former, was rendered evident. The solution was put
into two Woulfe’s bottles, the chlorine well washed and passed
through, until ultimately it bubbled through both portions without
absorption of any appreciable quantity. As soon as the common air
was expelled, the absorption of the chlorine was so complete in the
first bottle, that no air or gas of any kind passed into the second,
a proof that carbonic acid was not liberated in that stage of the
experiment. Continuing the introduction of the chlorine, the solution
in the first bottle gradually became yellow, the gas not being yet
visible by its colour in the atmosphere above the solution, although
chlorine could be detected there by litmus paper. Up to this time no
carbonic acid gas had been evolved; but the first alkaline solution
soon acquired a brighter colour, and now carbonic acid gas began
to separate from all parts of it, and passing over into the second
bottle, carried a little chlorine with it. The soda solution in the
first bottle still continued to absorb chlorine, whilst the evolution
of carbonic acid increased, and the colour became heightened.
After some time the evolution of carbonic acid diminished, smaller
quantities of the chlorine were absorbed by the solution, and the
rest passing into the atmosphere in the bottle, went from thence
into the second vessel, and there caused the same series of changes
and actions that had occurred in the first. The solution in the
first bottle was now of a bright chlorine yellow colour, and the gas
bubbled up through it as it would through saturated water.
4. When the chlorine had saturated the soda solution in the second
bottle, and an excess of gas sufficient to fill several large
jars had been passed through the whole apparatus, the latter was
dismounted, the solutions put into bottles and distinguished as
the saturated solutions of carbonated soda; they were of a bright
greenish-yellow colour, and had an insupportable odour of chlorine.
5. The saturated solution (4) was then examined as to the [p086]
change which had been occasioned by the action of the chlorine. It
bleached powerfully, and apparently contained no carbonated alkali:
but when a glass rod was dipped into it and dried in a warm current
of air, the saline matter left, when applied to moistened turmeric
paper, reddened it considerably at first, and then bleached it; and
this piece of paper being dried and afterwards moistened upon the
bleached part, gave indications of alkali to fresh turmeric paper.
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