6. A portion of the saturated solution (4) being warmed, instantly evolved chlorine gas, then assumed a dingy appearance, and ultimately became nearly colourless; after which it had an astringent and saline taste. Being evaporated to dryness at a very moderate temperature, it left a saline mass, consisting of much common salt, a considerable quantity of chlorate of soda, and a trace of carbonate of soda. This mixture had no bleaching powers. The dingy appearance, assumed in the first instance, was found to be occasioned by a little manganese which had passed over into the solutions, notwithstanding the care taken in evolving and washing the gas. 7. From these experiments it was evident that when chlorine was passed _in excess_ into a solution of carbonate of soda (3), the carbonic acid was expelled, and the soda acted upon as if it were caustic, a mixture of chloride of sodium and chlorate of soda being produced; with the exception of the small portion of carbonate of soda which, it appears, may remain for some time in the solution in contact with the excess of chlorine at common temperatures, without undergoing this change. The quantities of chloride of sodium and chlorate of soda were not ascertained, no doubt being entertained that they were in the well-known proportions which occur when caustic soda is used. 8. The Labarraque’s soda liquor which had been prepared as described (2), was now examined relative to the part the chlorine played in it, or the change the alkali had undergone, and was soon found to be very different to that which has been described, as indeed the experiments I had seen made by Mr. Phillips[32] led me to expect. The solution had but little odour of chlorine, its taste was at first sharp, saline, scarcely at [p087] all alkaline, but with a persisting astringent biting effect upon the tongue. When applied to turmeric paper, it first reddened and then bleached it. 9. A portion of the solution (2) being boiled, gave out no chlorine; it seemed but little changed by the operation, having the same peculiar taste, and nearly the same bleaching power as before. This is a sufficient proof that the chlorine, though in a state ready to bleach or disinfect, must not be considered as in the ordinary state of solution, either in water or a saline fluid; for ebullition will freely carry off the chlorine under the latter circumstances.