17. From an experiment made upon larger quantities of the Labarraque liquor, it would appear that the force of crystallization alone is sufficient to exclude the chlorine. A quantity was put into an evaporating basin, and left covered over with paper from July 16th to August 28th. Being then examined, a few large crystals were found covered over with a dense solution; the whole had the innocuous odour of Labarraque’s fluid, and the fluid the usual acrid, biting taste. The crystals being separated, one of the largest and most perfect was chosen, and being well wiped on the exterior, and pressed between folds of bibulous paper, was rubbed down in water, so as to make a saturated solution. This had no astringent taste like that of Labarraque’s fluid, or the mother-liquor, but one purely alkaline; and when applied to turmeric paper, reddened, but did not bleach it. Equal portions of this saturated solution and of the mother-liquor were then compared in bleaching power, acid being added to the former to assist the effect: it was found, notwithstanding that portions of mother-liquor must have adhered to the crystal, that its solution had not 1/21th part the power of the mother-liquor. This, in conjunction with the other experiments, is a striking instance of the manner in which the carbonate of soda acts, as a simple substance, with the chlorine in the solution. The crystal itself had never been in contact with the air: but whether it should be considered as the excess of carbonate of soda only which crystallized; or whether it is essential to the formation of these crystals that chlorine should simultaneously be given off into the air; or what would take place, if the water were abstracted without the evolution of chlorine, I have not determined. 18. Notwithstanding the perfect manner in which the chlorine may be thus separated by crystallization and slow evaporation to dryness, yet it is certain that by quick evaporation a [p091] substance apparently quite dry may be obtained, which yet possesses strong bleaching power. In one experiment, where, of two equal portions, one had been evaporated in the course of twenty-four hours to dryness upon the warm part of a sandbath, when compared with the former, it had not lost more than one-third of its bleaching power.