The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
19. With the desire of knowing what effect carbonic acid would have
on Labarraque’s fluid, and whether it possessed in a greater or
smaller degree the power of ordinary acids to expel the chlorine,
portions of the solution were put into two Woulfe’s bottles, and
a current of carbonic acid gas passed through them. The gas was
obtained from sulphuric acid and whitening in a soda-water apparatus,
and was well washed in water. The stream of gas brought away small
portions of chlorine with it, but they were not sensible to the
smell, and could only be detected by putting litmus paper into the
current. An immense quantity of gas, equal to nearly 1300 times the
volume of the fluid, was sent through; but yet very little chlorine
was removed, and the bleaching powers of the fluid were but little
diminished, though it no longer appeared alkaline to turmeric paper.
Air was then passed through the solution in large quantity; it also
removed chlorine, but apparently not quite so much as carbonic acid.
20. One other experiment was made upon the degree in which the
carbonate of soda in Labarraque’s liquor resisted decomposition by
the chlorine, even at high temperature. Two equal portions of the
fluid were taken, and one of them boiled rapidly for fifteen minutes;
both were then acted upon by sulphuric acid, blowing, and heat, as
described (11), and the two were then tested by nitrate of silver,
to ascertain the quantity of chlorine remaining: it was nearly
three times as much in the boiled as in the unboiled portion; and
by comparing this with the results before obtained (11), it will be
seen that, after boiling for a quarter of an hour, not more than a
twentieth part of the chlorine had acted upon the alkali, to form
chloride and chlorate.
21. It would seem as if I were unacquainted with Dr. Granville’s
paper upon this subject, published in the last volume of this
Journal, p. 371, were I to close my remarks without taking [p092]
any notice of it. Unfortunately, Dr. Granville has mistaken M.
Labarraque’s direction, and by passing chlorine, to “complete
saturation,” through the carbonate, instead of using the quantities
directed, has failed in obtaining Labarraque’s really curious and
very important liquid; to which, in consequence, not one of his
observations or experiments applies, although the latter are quite
correct in themselves.
_Royal Institution, Sept. 3, 1827_.
FOOTNOTES:
[31] See the last volume of this Journal, pp. 211, 460.
[32] See Vol. I. of this Journal, p. 461; and _Phil. Mag._ N. S., I.
376.
HIEROGLYPHICAL FRAGMENTS; _with some Remarks on_ ENGLISH GRAMMAR.
_In a Letter to the Baron William Von_ HUMBOLDT. By a Correspondent.
My dear Sir,
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