The Rare Earths: Their Occurrence, Chemistry, and Technology — John Shaqi
The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
For several reasons, the rare earth minerals[13] form a group of the
highest scientific interest. In the first place, they are generally of
very complex composition, more especially with regard to their rare
earth content. Thus, whilst it sometimes happens that one or other of
the two groups of oxides (the ceria and yttria groups) may predominate
to the complete exclusion of the second, it is no uncommon thing for a
species to contain almost all the elements of the rare earth family. On
the other hand, it is very uncommon for as much as 50 per cent. of the
rare earth content to consist of any one oxide. The usual case is that a
mineral contains chiefly yttria earths with some ceria earths, or _vice
versâ_, the two sub-groups being almost always complex mixtures of
several oxides, in which occasionally one may predominate. The
remarkable similarity in chemical behaviour of the rare earth elements,
and the difficulty of separating them, correspond to this peculiarity in
their occurrence.
[13] The phrase ‘rare earth minerals’ will be used whenever it is
desired to indicate collectively those minerals of which the yttria
and ceria earths form an important constituent, as contrasted to those
in which only traces of these oxides occur. Such minerals may often
contain titanium, zirconium, or thorium, and, for convenience, the
term may be taken to include the commoner zirconium and thorium
minerals, but not the commoner titanium minerals.
A second point of even greater interest is that the rare earth minerals
are as a general rule strongly radio-active; further, it only
occasionally happens that any mineral in which the rare earths do not
form an important constituent has more than the feeblest activity; the
exceptions being, of course, those uranium minerals which do not contain
rare earths. The connection may be pushed even further; for whilst it
appears that hardly any rock or mineral possesses absolutely no
radio-activity, it is equally worthy of notice that traces of the rare
earths, if not quite universal in the mineral world, are yet normally
found in the majority of common minerals. As a natural consequence of
their activity, the rare earth minerals are also as a rule rich in
helium. These facts and the problems which they open up will be treated
more fully in a later chapter.
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