The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Element. Equivalent. Atomic Weight.
Lanthanum 46 92
Cerium 46 92
Didymium 48 96
Yttrium 31 62
Erbium 56 112
the values for terbium being uncertain. If cerium be considered
trivalent in the cerous salts, its atomic weight becomes 138, that of
barium being 136. Mendelejeff placed cerium in Group IV, series 8, in
the position which it still occupies; he pointed out that the accepted
equivalent must be too low, and suggested that the atomic weight should
be at least 140, almost exactly the value accepted to-day.
This choice left the positions in Group III, series 8, horizontally
before cerium, and in Group IV, series 10, vertically below it (see
figure), to be filled by the two elements, lanthanum and didymium. No
chemical evidence being available to decide the choice, he provisionally
assigned didymium to the first (Group III, series 8), and lanthanum to
the second (Group IV, series 10) position, at the same time expressing
the opinion that didymium was probably a mixture of closely related
elements. Yttrium then fell into place in Group III, series 6, above
didymium, and erbium in Group III, series 10, below it. To the vacant
space above yttrium in Group III, series 4, he assigned the hypothetical
element Eka-boron, with atomic weight 44; this space is now occupied by
scandium, which corresponds almost exactly in properties to the metal
described by the Russian chemist. A part of the table illustrating these
positions is shown in Fig. 4.
The determination of the specific heats of the metals by Hillebrand and
Norton in 1875, whilst confirming the trivalency of the elements,
rendered it necessary to alter the position of lanthanum, which was
placed in Group III, series 8, instead of didymium, which was thus left
without a place. This first indication that all the rare earth elements
could not be fitted into the table without difficulties was soon
followed by the discovery of several other members of the group, for
which places could not easily be found.
[Illustration:
Public-domain text, read in full here on John Shaqi.
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