The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
In support of this arrangement, he quotes the fact that some of the
elements appear to be able to form higher oxides in the presence of
other oxides, which act as oxygen carriers (see pp. 174, 177-8), though
these higher oxides are certainly not salt-forming. He also deduces,
from the rates of hydrolysis of the sulphates, that the elements fall
into two parallel series, according to the strengths of the hydroxides
as bases, on which ground he justifies the distribution throughout
series 8 and 9. There can be no doubt, however, that this disposition is
far less in accordance with the behaviour and properties of the rare
earth elements than is the first arrangement, which places them in a
transition zone between barium and tantalum; it is impossible, for
example, to reconcile the properties of praseodymium with those of
columbium and tantalum, or to find the slightest analogy between
neodymium and molybdenum or tungsten, as the second arrangement
requires.
The analogy of the rare earth group to the elements of Group VIII has
been pointed out by many authors.[179] On the ground that the rare earth
elements cannot be spread over the table in series 8-10, Steele[180]
favours the early classification of Thomsen, according to which the
elements are divided into three groups. The first, corresponding to
Groups I and II of Mendelejeff’s table, consists of two sub-groups, each
containing seven elements[181]; the second, corresponding to the first
two long series of the periodic table, has two sub-groups, each of
seventeen elements, of which the first and last seven are
analogous--these elements fall into the same groups in the periodic
table--whilst the middle three are interperiodic. These interperiodic
elements are those which Mendelejeff places in Group VIII. The third
division consists of one (or two) group(s) of thirty-one elements; here
again, the first and last seven are analogous, whilst the interperiodic
elements, which are seventeen in number, include the rare earth metals.
[179] Compare Biltz, _Ber._ 1902, ~35~, 562.
[180] _Chem. News_, 1901, ~84~, 345.
[181] The inert gases are not included.
Steele’s idea has been extended by Werner,[182] who has drawn up a table
to illustrate it. In this classification, the elements are arranged in
order of atomic weight, but arbitrary gaps are left in such a way that
similar elements may fall into the same vertical columns, as in the
periodic table. The arrangement has the advantage that the interperiodic
elements, consisting of the rare earth elements and the elements placed
in Group VIII of the periodic table, here do fall in the middle of their
respective periods, but it has several drawbacks, and does not represent
the transition of properties from element to element so well as the
helical representation of the periodic table, which brings out most
clearly the true relations between the elements, and the anomalous
position of the rare earth metals.
[182] _Ber._ 1905, ~38~, 914.
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