The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Electropositive Elements, above plane of paper, black letters on white
ground. Electronegative Elements, below plane of paper, white letters on
black ground. Intermediate Elements, in plane of paper, black letters on
sectioned ground.]
[Illustration:
+---------+--------+--------+--------+--------+--------+--------+
| Group | III. | IV. | V. | VI. | VII. | VIII. |
| |A B|A B|A B|A B|A B| |
+---------+--------+--------+--------+--------+--------+--------+
|Series 6|~Yt~ |~Zr~ |Cb |Mo | |Ru Rh Pd|
| | | | | | | |
| „ 7| In| Sn| Sb| Te| I| |
+---------+--------+--------+--------+--------+--------+--------+
| „ 8|~La~ |~Ce~ |~Pr~ |~Nd~ |~Sa~ |~Eu~ |
| | | | | | | |
| „ 9| ~Gd~| ~Tb~| ~Dy~| ~Ho~| ~Er~|~Tm~~Yb~|
+---------+--------+--------+--------+--------+--------+--------+
| „ 10|~Lu~ | |Ta |W | |Os Ir Pt|
| | | | | | | |
| „ 11| | | | | | |
+---------+--------+--------+--------+--------+--------+--------+
FIG. 6.--PART OF THE PERIODIC TABLE, SHOWING THE POSITIONS ASSIGNED TO
THE RARE EARTH ELEMENTS BY BRAUNER IN 1908]
Brauner’s conception is also in accord with the physical properties of
the elements and their compounds. These vary continuously throughout the
group, and show nowhere the sudden transitions which are characteristic
of other series in the table. Benedicts[177] has collected all the data
bearing on the atomic volumes, and finds that those also vary
continuously, with rise in the atomic weights, within quite small
limits, all lying between the values for barium and tantalum. In face of
all the evidence furnished by physical and chemical properties, however,
Brauner[178] has recently reverted to an idea which he put forward in
1881, according to which lanthanum and cerium are placed as usual in
Groups III and IV, series 8, whilst the other elements are distributed
in order throughout the remaining groups, as shown in Fig. 6.
[177] _Zeitsch. anorg. Chem._ 1904, ~39~, 41.
[178] _Monats._ 1881, ~3~, 1; _Zeitsch. Elektrochem._ 1908, ~14~, 525.
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