The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
(3) Potassium azide, KN₃, throws down thorium hydroxide from boiling
neutral or faintly acid solutions. Ceric salts if present must be
previously reduced; zirconium must be previously removed by oxalic acid.
(4) Precipitation may be effected with potassium iodate in strong nitric
acid solution. Here also ceric salts must be reduced before applying the
test. Zirconium also gives the test; the precipitate must therefore be
washed and warmed with oxalic acid, in which thorium iodate is
insoluble, whilst zirconium iodate is soluble.
The methods of estimating thorium are given in Chapter XVIII.
PART III
THE TECHNOLOGY OF THE ELEMENTS
CHAPTER XVII
THE INCANDESCENT MANTLE INDUSTRY--HISTORICAL AND GENERAL INTRODUCTION
The group of elements which we are considering can be divided, from the
point of view of technical application, into two classes. The first of
these contains one element only, titanium, which in its technology, as
in its chemistry, stands apart from the others; it will, accordingly, be
treated in a separate chapter. The second class contains the yttrium and
cerium metals, with zirconium and thorium; the technical importance of
these elements is due chiefly to the use of their oxides in
illumination, to a small extent in Nernst lamps, and to a much greater
extent in the so-called Incandescent Lighting. The manufacture of
incandescent mantles[487] is a large and ever-extending industry,
intimately bound up with the older process of coal-distillation, with
its innumerable ramifications; indeed, it may be said that but for the
ingenious invention of Dr. Auer, illumination by means of coal-gas would
to-day have been almost obsolete. The discovery which resulted in the
production of the familiar incandescent mantle of the present day may be
regarded as the culmination of a century’s effort to increase the value
of coal-gas as an illuminating agent. In the present chapter it is
proposed to outline the history of these endeavours, and to give a short
general account of Auer’s work and its results.
[487] The term ‘incandescent mantle’ is not, perhaps, scientifically
very desirable. It is used here, not only on account of its general
acceptance, but also because there seems to be no brief and convenient
term which might be used in its stead.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account