The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Soon after the introduction of gas as an illuminating agent it was
realised that the luminosity of the flame is dependent on the presence
of solid particles, which by the heat of combustion of the gas are
raised to a temperature at which they emit radiations of wave-lengths
corresponding to the ‘luminous rays’ of the spectrum. A non-luminous
flame of sufficiently high temperature, therefore, can be rendered
luminous by the introduction of suitable solids, and numberless
investigators have striven, during the past century, to discover the
most suitable method of increasing the luminosity of a flame in this
way. The luminosity of the ordinary ‘bats-wing’ or ‘flat’ flame, now so
rapidly going out of use, is due to the presence in the outer zone of
the flame of heated particles of carbon, produced by the
decomposition--or partial combustion--of ‘dense’ hydrocarbons, _i.e._ of
hydrocarbons having a high percentage of carbon. Ordinary coal-gas
consists largely of a mixture of hydrogen and methane, both of which
burn with practically non-luminous flames, with small quantities of
olefines, acetylenes, etc., to which the luminosity is chiefly due. It
would appear, then, that by the introduction of dense hydrocarbons, a
gas of poor illuminating power might be made much more valuable as a
source of light. On the other hand, it is also apparent that the same
end might be achieved by the introduction into a non-luminous or feebly
luminous flame of an altogether foreign substance, introduced as such,
and not continuously consumed, as is the carbon in the former method.
Both these directions of improvement have been followed; since, however,
the results achieved by the latter method have become recently of far
greater importance, the applications of the first method will be
dismissed quite briefly, and the history of the second will then be
treated somewhat fully.
The first important attempt to increase the illuminating power of gases
burning with feebly luminous flames was that of Faraday, who in the
course of an investigation into the causes of the variations in
luminosity of ‘portable gas,’ discovered benzene, or bicarburet of
hydrogen, as he called it, in 1826. In 1830 an engineer named Dunnovan
undertook to illuminate Dublin by means of water-gas[488] which he
‘carburised’ by addition of dense hydrocarbons. During the latter half
of the nineteenth century this method became of some importance. It has
been applied, in particular, to enrich the ‘natural gas’ of Ohio, North
America. The dense hydrocarbons necessary for this purpose are obtained
by the process known as ‘cracking.’ The viscous residues from the
distillation of the mineral oil of the district are allowed to drop into
a brick chamber, of which the walls are raised to a bright red heat, and
the dense hydrocarbons which are evolved are removed by a current of the
gas to be enriched. In this way a gas of relatively high illuminating
power is obtained.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account