The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The more important attempts to secure arrangements by which the
radiations of heated solids could be used for illumination have now been
outlined and the ground cleared for the consideration of the work of
Baron von Welsbach. There remain yet to be mentioned, however, two
attempts which are of especial interest in view of that work. The first
is that of Frankenstein, who in 1849 made use of a ‘Light-multiplier’
obtained by impregnating gauze with a paste of chalk and magnesia ground
with water. The second is that of Edison, who proposed (1878) to utilise
the observations of Bahr and Bunsen (1864) and of Delafontaine (1874),
of the remarkable incandescence exhibited by the yttria and erbia
earths, and the terbia earths, respectively, when heated; he suggested
the employment of a mantle of platinum wire covered with zirconia and
the oxides of the rare earth metals, a proposal similar to that put
forward nearly forty years earlier by Cruickshank.
About the year 1880 Dr. Carl Auer began the study of the rare earth
elements. The chemical aspect of his work has already been dealt with
(_vide_ p. 168); but the results obtained by the technical application
of his observation that threads of cotton, impregnated with a solution
of salts of the elements, leave after ignition a coherent ash of oxide,
which glows brightly when heated, have been of far greater importance
than the purely scientific aspect, valuable though that is. A series of
experiments soon showed that a fabric of suitable shape, impregnated
with a solution of nitrates or acetates of the rare earth elements,
after being dried and drawn together at one end by means of a platinum
wire, can be ignited in a Bunsen flame in such a way as to leave a
coherent skeleton of the earth oxides, which can be formed and hardened
by suitable manipulation with a high temperature burner; the mantle so
prepared, when suspended from a lateral support in a Bunsen flame, gives
a light of considerable intensity, the colour varying with the oxides
employed from green to orange tints.
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