The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
A new development was made in 1880 by Clamond. He prepared a paste by
grinding up calcined and powdered magnesia with a concentrated solution
of magnesium acetate; by forcing this through a press he obtained a
ribbon which was then wound crosswise on a wooden shaper, dried
carefully, and ignited. In his later experiments twenty per cent. of
zirconia was added to the magnesia. The mantle was supported in a
platinum cage and heated in the flame of a mixture of coal-gas and
heated air. This mantle gave an intense light, but was too fragile for
extended use. In the following year, Lundgren patented a process by
which lime, magnesia, and zirconia, made into a paste by the addition of
gum, were forced through a press, and the resulting thread wound on a
graphite-covered shaper. The mantle so obtained was stable, and gave an
intense white light, but after having been heated for some time the
oxides crumbled to powder. A modification of this process was introduced
by Knöfler in 1894, in an attempt to use a cellulose solution containing
rare earth salts; this was forced through jets, and the cellulose
precipitated as a continuous thread from which the mantle was made. A
further modification of Knöfler’s process by Plaisetty in 1901 was
technically successful; but these developments must be taken up in a
later chapter (_vide_ p. 307).
In 1883 a process was patented by Fahnehjelm in Stockholm, by which for
the first time a cheap and stable mantle of considerable efficiency was
produced, and which, but for the advent of the Auer mantle, would
undoubtedly have been commercially successful. Fahnehjelm’s mantle
consisted of an arrangement of needles or lamellæ of magnesia, lime,
zirconia, etc., suspended over a burner. The plates and needles were
usually arranged in the form of a comb of suitable shape, and were found
to give an intense light, and to be long-lived. In later forms the combs
were made of rods of magnesia dipped into solutions of chromium salts.
The great disadvantage of this invention lay in the fact that the combs
required to be heated in the flame of water-gas, in order to secure a
good incandescence; had it been possible to attain a sufficiently high
temperature by the use of coal-gas, it is doubtful whether the Auer
mantle would have ever been evolved.
Public-domain text, read in full here on John Shaqi.
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