The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
It has been already stated in Part I (_vide_ p. 73) that a strongly
radioactive product. Radiothorium, has been obtained from the mineral
thorianite. This body is produced by the atomic degradation of thorium,
and an intermediate body, mesothorium, has been found to be formed
during the change. Mesothorium is a substance which, though it appears
to be chemically identical with radium, has an activity equal to three
hundred times that of radium, and when in equilibrium with its
degradation products the ‘rays’ it emits are very similar to those of
the latter element. Since mesothorium is a degradation-product of
thorium, it occurs in minute quantities in all thorium minerals, and by
reason of the possibility of using it as a substitute for radium, its
extraction becomes a matter of importance. Soddy[498] has shown that if
a barium compound be added to monazite before the treatment with
sulphuric acid, the mesothorium remains with the barium sulphate; this
is readily separated from the heavy unchanged grains of sand, and is
purified, and finally obtained as chloride by treating the solution with
hydrogen chloride. On recrystallisation of the barium chloride, the
active products are concentrated in the less soluble part, and it is
possible to prepare on the commercial scale a mixture which, though it
contains only 0·25 per cent. of mesothorium, has an activity equal to
that of pure radium bromide. This mixture contains 25 per cent. of
radium compounds, radium being present as an original constituent of
monazite; owing to the chemical identity of radium and mesothorium,[498]
the latter cannot be separated, but Soddy, by removal of much of the
barium compound in the laboratory, has obtained a product four times as
active as the pure radium salt.
[498] _Proc. Chem. Soc._ 1910, ~26~, 336, and _E._ 25504, November,
1910. See also Hahn, _Chem. Zeitg._ 1911, ~35~, 845.
It is probable that the treatment of monazite will in the future be
modified by the addition of barium sulphate before the sulphuric acid
decomposition, to allow of the commercial extraction of its mesothorium.
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