The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The prepared fabric is shaped on a suitable form, and removed by a
holder, which supports it from the asbestos thread; a flame is then
applied to the head. The burning-off proceeds readily, once started;
when the upper half has been incinerated, the flame is removed. The
weight of the unburnt portion prevents too rapid contraction taking
place at first; when the flame is removed, the glow spreads slowly
downwards, and the shrinking is thus kept as uniform as possible. The
operation must be carried out under a ventilating hood. The organic
material of the fabric is completely oxidised, and the nitrates are
converted into oxides, which retain the exact shape of the original
fibres. The skeleton now undergoes the process of shaping and hardening,
for which a ‘radial’ blowpipe flame is used. The burnt-off product is
placed over this; the gas is supplied at an initial pressure of only a
few inches of water, which is increased towards the end of the
operation. The process commences at the head, the mantle being slowly
lifted and rotated so that it is shaped and hardened along the whole
length. By this means the oxide skeleton is not only suitably shaped,
but is rendered considerably more elastic and resistant. For inverted
mantles, of course, specially shaped burners are required. The eyes of
the operators must be protected from the glare by shades of green glass.
Recently the processes of burning-off and hardening have been carried
out by means of the same burner.
Where machines are employed, the prepared fabrics are burnt off on wire
shapers, usually in rows of ten; mechanical arrangements for continuous
ignition and motion and, in the hardening, for continuous elevation of
the ash-skeleton, are in use, but the finished mantles maintain a
uniform good quality only when the structure of the fabric and the
earlier processes have been absolutely uniform.
~Collodinisation.~--The burnt-off mantle is now ready for use, but is
far too fragile for transport. A method has therefore to be found by
which the finished product can be protected for a time without detriment
to its use for illumination. Mantles of artificial silk, particularly
those for use in high-pressure lamps, are sometimes sent out without
having undergone the final processes of burning off and shaping, which,
in this case, must be carried out on the consumer’s burner. ‘Inverted’
mantles also were formerly sent out after impregnation and drying. In
this condition, of course, the mantles are readily packed and
transported, and there is the additional advantage that the duty on the
unburnt product is very much less than that on the finished mantle.
Public-domain text, read in full here on John Shaqi.
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