The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
One of the earliest of Auer’s patents (_vide supra_, p. 271) protected
the process of collodinisation, which is now extensively employed. The
oxide skeleton is dipped into a solution of collodion (the mixed lower
nitro-derivatives of cellulose, or cellulose nitrates) in a mixture of
alcohol and ether, to which, to prevent shrinkage on drying, a little
camphor is added. On account of the inflammability of the mixture, the
ethyl alcohol and ether are occasionally replaced by a mixture of methyl
alcohol and acetone, but with this less volatile mixture, drying of
course is slower. After dipping, the solvents are removed in a current
of air, leaving the mantle coated with an exceedingly thin film of
collodion, which increases enormously its power of resisting shock and
vibration. This film is not removed until the mantle is placed on the
consumer’s burner, when on the application of a match it ignites
instantly and burns away, leaving the oxide skeleton in the condition to
which it was brought in the final stage of hardening and shaping in the
factory. The process is now used for almost all kinds of mantles, having
been successfully applied in Germany in recent years to those made from
artificial silk. The addition of small quantities of various inorganic
salts, _e.g._ nitrates of zirconium, magnesium, platinum, thorium, etc.,
to the collodion solution, has been proposed; these salts make the
collodinised product extremely resistant, but have a very harmful effect
on the oxide ash when the collodion has been burnt off.
The collodinised mantles are cut to length on a trimming machine, and
are then ready for packing.
* * * * *
The present chapter may be concluded with a bare mention of a few
disconnected details, selected from the great mass of proposals,
suggestions, and developments which have sprung up round the
incandescent mantle industry.[520]
[520] For a complete account of the mechanical developments, the
reader is referred to the monograph ‘Beleuchtung und Lichtmessung,’ by
Dr. Börnstein, in Dammer’s _Chemische Technologie der Neuzeit_,
Stuttgart, 1910-11, ii. 243-266.
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