The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Whilst it is very generally agreed that the addition of titanium results
in the production of much stronger and more durable products, the
question of the precise effect obtained is by no means definitely
settled. The experimental work, whilst pointing on the whole to the
superiority of titanium-treated steel, is by no means conclusive; in
some cases, indeed, it is conflicting. Thus the micro-photographs
obtained by von Maltitz[620] and Venator[621] show that the
titanium-treated steel has a far cleaner fracture and far more
homogeneous structure than steels not so treated; on the other hand, the
micro-photographs of Treuheit[622] show practically no improvement in
structure for the titanium steel. The exhaustive tests of the first two
authors, again, and the experiments of numerous railways in the use of
titanium steel rails,[623] demonstrate clearly that the treatment
results in improvement in strength and durability of the product; but
the work of Otto[624] proves equally clearly that his products did not
differ markedly, whether titanium-treated or not, and he is of opinion
that the rail tests were not sufficiently prolonged or searching to be
considered conclusive. It is nevertheless to be considered certain that
the use of titanium does cause a marked improvement in the quality of
the steels obtained, and especially in the durability of rails. The
negative results obtained by some authors may be explained, firstly, on
the ground that no tests are conclusive unless carried out with steel
from the one bath, one half of which has been treated with titanium, and
the other half not so treated; secondly, that the ferro-titanium must be
incorporated with the metal, and must not be suffered to be taken up by
the slag, and so lost; and thirdly, that the bath must be allowed to
remain for some minutes after treatment, in order that the reaction may
be complete, and the titanium-bearing slag allowed to rise to the
surface. When these conditions are carefully observed, experiment shows
that marked improvement in the quality of the steels produced is
effected.
[620] _Stahl Eisen_, 1910, ~29~, 1593.
[621] _Ibid._ 1910, ~30~, 650.
[622] _Ibid._ 1910, ~30~, 1192.
[623] _Vide_ Dudley, _J. Ind. Eng. Chem._ 1910, ~2~, 299; also _Cass.
Mag._ 1911, ~40~, 483.
[624] _Vide_ abstract in _Stahl Eisen_, 1912, ~32~, 1497.
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