The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
As to the actual nature of the effect produced, it is generally believed
that titanium acts merely as a cleansing agent, freeing the metal from
occluded or combined gases, and removing blow-holes, so producing a
denser and more homogeneous structure, with consequent improvement in
properties. The added titanium is usually found entirely in the slag,
so that it appears certain that it does not alloy, but merely purifies.
It certainly acts as a powerful and rapid deoxidiser, removing the last
traces of the gas which have escaped the action of the manganese,
silicon, etc., with which steels are now generally treated. Many
authorities, on the ground of analyses, and of the known affinity of
titanium for nitrogen, believe that it very largely reduces the
nitrogen-content,[625] which is so harmful; this, however, is still an
open question.[626] It is stated that if excess of titanium is used, so
that small quantities--0·05-0·20 per cent.--remain in the finished
steel, the toughness and durability are further increased;[627] but as a
rule, manufacturers prefer to work with smaller quantities, so that no
free titanium remains in the product.
[625] _Vide_ von Maltitz, _loc. cit._
[626] _Vide_ Venator, _loc. cit._
[627] _Vide_ _Bull. Imp. Inst._ 1911, ~9~, 134.
* * * * *
The preparation of alloys of titanium with almost all the commoner
metals is protected by patent, but few of these are of technical
importance. Small quantities of titanium are said to improve very
considerably the properties of copper and its alloys, the brasses,
bronzes, etc., especially in castings. The addition is usually made in
the form of an appropriate titanium alloy, prepared by reduction of the
mixed oxides with carbon in an electric furnace, or treatment of the
mixed oxides, together with the alloying metal, with aluminium under
similar conditions.[628] The titanium-silver alloys obtained in this
way[629] are said to improve greatly the structure of silver, by
preventing the familiar ‘spitting’ as the fused metal cools.
[628] _Vide_ Rossi, _U. S. P._ 986505, March, 1911; 935863, October,
1909, etc.
[629] Rossi, _U. S. P._ 1024476 and 1025426, August, 1912.
An interesting process, which has been patented by Rossi,[630] recalls
the method of formation of cementation steels. He has found that if a
metal be loosely covered with its alloy with titanium, in a finely
powdered condition, and the whole heated, the titanium diffuses into the
metal, to a depth and concentration which vary with the temperature and
the time of heating. He suggests that in this way a metallic body may be
toughened and strengthened at any desired point, _e.g._ steel for
armour-plate at the surface. Whether the process will be of any
technical value or not can only be shown by experiment.
[630] _U. S. P._ 986504, March, 1911.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account