The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
It is infusible before the blowpipe, but loses its colour; some
varieties glow and increase in density (see p. 38). In some varieties
also the colour changes or disappears rapidly on exposure to sunlight,
and is often restored on keeping in the dark. These phenomena of colour
change have been attributed variously to alteration in the state of
oxidation of the iron present, and to the presence of organic matter. It
seems probable that either cause or even both may be at the root of the
change in particular cases.
On account of the hardness, unalterability, and strong refraction and
double refraction, good crystals of zircon are used as gems. The two gem
varieties, Hyacinth and Jargon, are found chiefly in the gem gravels of
Ceylon. It was in a zircon from Ceylon that Klaproth discovered the new
earth, Zirconia, in 1789.[51] In 1795 he found the same earth in
hyacinth, and so showed the two to be identical.
[51] _Schriften der Gesellschaft naturforschender Freunde in Berlin_,
1789, vol. 9.
Artificial crystals of zircon have been obtained by the action of
silicon tetrachloride and silicon tetrafluoride on zirconia, and by the
action of zirconium tetrafluoride on silica at high temperatures.
Zircon is one of the most widely distributed minerals known, though
usually it occurs in very small quantities. Good crystals have been
found in New Zealand, in Ceylon, at Miask in the Urals, and in North
Carolina. This last deposit has been worked commercially for the
extraction of zirconia for Nernst lamps (_vide_ p. 320). It occurs in a
decomposed felspar in a pegmatite dyke in the Archæan gneiss near
Zirconia, Henderson Co., and can be easily extracted by picking or
washing, after crushing if necessary. Should there ever be a
considerable demand for zirconia, it could doubtless be saved as a
by-product in the extraction of thoria from monazite sands (_q.v._),
zircon being very generally found in those sands (see below).
Zircon is common in crystalline rocks, limestones, schists, syenites,
granites, etc. It is a constant accessory constituent in the acid
igneous rocks, especially in the more acid eruptive rocks. It is readily
detected under the microscope by the pleochroic haloes with which the
tiny crystals are surrounded; these have been shown by Joly to be due to
alteration of the surrounding rock by the radiations emitted by the
radio-active constituents of the zircon. It also occurs as a constituent
of those sands which are formed by the erosion of the igneous rocks in
which it is enclosed, and hence it almost invariably accompanies
monazite in the so-called monazite sands.
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