The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Common forms are--the pinakoid _c_ {111}, prisms _a_ {101}, and _m_
{211}, and pyramids _r_ {100} and _e_ {110}. _c_ ∧ _r_ = 31° 22´.
Habit tabular parallel to _c_, rhombohedral with _e_ prominent, or
prismatic with _a_ prominent.
Cleavage ∥ _c_ very good, ∥ _a_ difficult.
The colour is brown or red to brownish- or bluish-red. Brittle.
Hardness 5 to 5¹⁄₂; sp. gr. 2·92 for eudialyte, 3·0 to 3·1 for
eucolyte.
The double refraction is strong, being positive for eudialyte, negative
for the Norwegian variety, eucolyte. From careful microscopic
examination, Ramsay has found that zones of positive and negative
birefringence, as well as isotropic (singly-refracting) zones can occur
on the same crystal, and he suggests that the mineral is really composed
of two isomorphous compounds forming mixtures. In view of the continuous
variation of optical properties in an isomorphous series like the
felspars, such an explanation seems doubtful. The optical behaviour of
minerals is very often anomalous, and the phenomena in this case are
probably due to repeated twinning, with some alteration in the double
refraction, or to the lamellar intergrowth of two varieties having
slightly different optical properties.
On heating, the mineral evolves moisture and readily fuses. It is easily
attacked even by dilute acids, being named by Strohmeyer (1819) on
account of this property. The dilute hydrochloric acid solution reddens
turmeric paper--a test for the presence of zirconium.
It is found in Greenland, usually embedded in felspar, in Norway, in
Lapland and in Arkansas, being generally associated with minerals rich
in alkalies, _e.g._ ægirine, ælæolite, nepheline, sodalite,
arfvedsonite, etc.
~Beckelite.~--This is a mineral similar in composition to eudialyte,
though not so complex, and of more recent discovery.[54] It is a
silicate of ceria earths and lime, in which zirconia replaces silica;
the oxygen ratio (_i.e._ ratio of oxygen in basic oxides to oxygen in
acid oxides) is 3 : 1, and the formula Ca₃R´´´₄(Si,Zr)₃O₁₅, where R =
rare earth metals, chiefly of the cerium group. It is thus a salt of an
acid H₁₈Si₃O₁₅ [= 3H₆SiO₅ = 3(3H₂O,SiO₂)] with zirconium and silicon
vicarious.
[54] _Abstr. Chem. Soc._ 1905, ~88~, ii, 177.
The crystals appear to belong to the cubic system, occurring in cuboid
grains, and in octahedra and dodecahedra. It is brown, and isotropic,
with cubic cleavage. Sp. gr. = 4·15.
It is soluble in hot hydrochloric acid, even after ignition; the
solution gives the turmeric test for zirconium.
It was found in a dyke in an ælæolite syenite, near the Sea of Azov.
* * * * *
The following minerals (see list) are also to be placed in the class of
mixed silicates:
_Arfvedsonite_ and _cataplejite_, complex zircono-silicates.
_Hiortdahlite_ (Guarinite) and _Lavenite_, zircono-silicates with
fluorine.
_Caryocerite_, _Melanocerite_ and _Steenstrupine_, complex
fluosilicates.
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