The Rare Earths: Their Occurrence, Chemistry, and Technology — John Shaqi
The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
On account of the difference in colour and composition, a large number
of varieties are distinguished. The ordinary yellow and brown varieties
are known indifferently as sphene or titanite. _Ligurite_ has an
apple-green colour; _Semeline_ is a greenish form named from a fancied
resemblance to flax seed. _Lederite_ is a brown variety of tabular
habit; _Greenovite_ is rose-coloured, and contains manganese.
_Alshedite_ and _Eucolite-Titanite_ are rich in the trivalent metals;
_Grothite_ is a brown variety containing a considerable percentage of
ferric iron. _Yttrotitanite_, which contains a high proportion of rare
earths, is usually treated as a separate species (see above).
_Titanomorphite_ and _Leucoxene_ are white amorphous varieties chiefly
produced by alteration of rutile and ilmenite.
Titanite is a fairly widespread mineral; as an accessory rock
constituent it is common in the massive plutonic rocks in tiny crystals,
readily distinguished under the microscope by the high refraction and
birefringence, whilst in large embedded crystals it occurs in many
granular limestones, and in plutonic acid, as well as in some
metamorphic rocks. In good crystals it is found in many parts of
Switzerland and the Alps, in Dauphiné, the Tyrol, Piedmont, the Urals,
South Norway, and other European localities; it is also widely
distributed in the United States and Canada.
The mineral is important as a valuable source of titanium.
* * * * *
The class of Titano-silicates is a very large one, and might be extended
almost at will by the inclusion of the numerous silicates which contain
titanium. Owing to the frequency with which small quantities of silica
are replaced by titanium dioxide, almost all the commoner silicate
minerals contain the latter oxide, so that titanium is one of the most
widely distributed of the elements. Relatively very few, however, of the
titanium-bearing minerals contain the element in considerable
quantities, and only two or three have any importance as commercial
sources of titanium compounds.
Only those additional titano-silicates which contain titanium as an
important constituent are mentioned below; short accounts will be found
in the alphabetical list.
_Johnstrupite_, _Mosandrite_, _Rinkite_, _Rosenbuschite_ and
_Tscheffkinite_ are complex titano-silicates containing yttrium or
cerium metals.
_Astrophyllite_, _Leucosphenite_, _Molengraafite_, _Neptunite_ and
_Rhönite_ are complex titano-silicates free from rare earth elements.
_Benitoite_ is a simple titano-silicate of barium; _Ænigmatite_ and
_Narsarsukite_ contain iron and sodium; _Lorenzenite_ has sodium and
zirconium. _Schorlomite_ is a titaniferous garnet. A variety of olivine
rich in titanium (_Titanium Olivine_) is also known.
(_b_) THE TITANATES
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