The Rare Earths: Their Occurrence, Chemistry, and Technology — John Shaqi
The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Rammelsberg gives the formula R´´₃R´´´₂(Cb,Ta)₆O₂₁, where R´´ =
(Fe´´,Ca,UO₂), and R´´´ = rare earth metals. Groth regards it as
essentially a pyrocolumbate (tantalate) of rare earth metals
R₄[(Cb,Ta)₂O₇]₃ the iron, calcium and uranium being more or less
accessory constituents. Des Cloizeaux considers the formula indefinite.
The mineral has also been found to contain tin, thorium, germanium, and
helium. The yttria earths usually predominate (11·9 to 18·9 per cent.),
the percentage of ceria earths being low (2·4 to 5·2 per cent.). The
yttria earths contain the very rare oxide samaria.
The mineral is radio-active.
Crystal system--orthorhombic; _a_ : _b_ : _c_ = 0·5456 : 1 : 0·5178.
Forms--macro- and brachy-pinakoids _a_ {100} and _b_ {010}; prisms _m_
{110} and _h_ {120}, the macrodome _e_ {101}, and pyramids _p_ {111}
and _v_ {231}.
Angles--(100) ∧ (110) = 28° 37´; (001) ∧ (101) = 43° 30´; (001) ∧
(011) = 27° 22¹⁄₂´.
Habit usually prismatic, with _e_ prominent; sometimes tabular
parallel to _a_ or _b_. Cleavage ∥ _b_, imperfect. The faces are
usually rough. The mineral commonly occurs massive, and in flattened
grains embedded in granite. Conchoidal fracture. Brittle. Hardness 5
to 6; sp. gr. 5·6 to 5·8.
Colour velvet-black, streak reddish-brown. Opaque even in thin films.
Before the blowpipe it fuses at the edges; with borax it gives an iron
bead. It is decomposed by boiling concentrated sulphuric acid, better by
fusion with potassium hydrogen sulphate, and leaching the residue with
dilute hydrochloric acid--this leaves the insoluble oxides Cb₂O₅ and
Ta₂O₅. On heating it glows, with decrease in specific gravity (cf. p.
38).
Samarskite occurs with other columbo-tantalates in felspar, or in veins
in granite, near Miask in the Urals, near Quebec in Canada, and in
Mitchell County, North Carolina. From the last-named locality, masses up
to twenty pounds in weight have been obtained.
The mineral was first discovered in the Urals by Ewreinoff, captain of a
corps of Russian mountain engineers. He sent a specimen for
identification to the mineralogist Gustave Rose, who pronounced it to be
a tantalate of uranium containing manganese, and called it
Urano-tantalite.[60] In 1847 the chemist Heinrich Rose, brother of
Gustave, in the course of his researches on tantalic ‘acid’ (oxide),
analysed a specimen. He found the composition given above, and renamed
it Samarskite,[61] in honour of the Russian engineer who furnished him
with the specimen for analysis.
[60] _Pogg. Ann._ 1839, ~48~, 555.
[61] _Ibid._, 1847, ~71~, 157.
In 1907, Brögger[62] announced that _Annerödite_, of which he had
published an account as a new species in 1881, was a parallel growth of
the mineral columbite, (Fe,Mn)Cb₂O₆, on samarskite.
[62] _Abstr. Chem. Soc._, 1907, ~92~, ii. 885.
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