The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Rare earth minerals found in the monazite sands include
xenotime, fergusonite, samarskite, gadolinite, and allanite. The
remaining minerals are oxides of iron and tin, with, of course, a
considerable amount of quartz.
It is apparent, from what has been said above, that monazite will be
concentrated with the heaviest constituents of the rocks from which it
is derived. Very often, indeed usually, these rocks are precisely those
in which gold occurs, disseminated sometimes in tiny particles,
sometimes collected into nuggets in veins of quartz and pegmatitic
minerals. The erosion of these rocks concentrates the gold with the
heaviest minerals; and hence it happens that monazite is an almost
universal constituent of the gold- and gem-bearing sands and gravels. In
the Carolinas and in Brazil, monazite is found in the gold washings; and
though in the past the two have always been extracted separately, the
gold first and the monazite from the washings or tailings, there appears
to be no reason why a system calculated to extract both--where, of
course, the content is high enough--should not be put into operation in
the future.
A chemical test affords the only reliable method of detecting monazite
in a sand. A little of the sand is washed with water to remove the
lighter minerals and warmed with concentrated sulphuric acid. A few
drops of the liquid are poured off, evaporated to small bulk, and one
drop placed on a glass plate. This is placed under a microscope and one
drop of a concentrated solution of sodium acetate is added. If monazite
is present in the sand, tiny pointed oval crystals of sodium cerium
sulphate will separate.
On the commercial scale, monazite is extracted from the sands only, in
the manner described below. An effort was made in North Carolina in 1906
by the British Monazite Company, representing the South Metropolitan Gas
Light Company of London, to extract monazite from the rock in which it
occurs disseminated. The rock was crushed and powdered, and the monazite
separated by washing off the lighter particles on concentration tables
(see below). In the same year, however, the price of thorium nitrate was
suddenly lowered 50 per cent. by the German Thorium Syndicate, which
largely controls the Brazilian output of monazite, and the British
company stopped operations in 1907. At present it may be said that only
the sands are available for profitable extraction.
Public-domain text, read in full here on John Shaqi.
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