The chemistry of the rare earth elements begins in the year 1794, with Gadolin’s discovery of the new oxide ‘Ytterbia,’ for which the name Yttria was subsequently proposed by Ekeberg, and generally adopted (see Chapter I, and under Gadolinite, p. 35). The discovery of Ceria followed in 1804 (see under Cerite, p. 32). The classical work of Mosander, carried out between 1838 and 1842, showed the complex nature of the new oxides. From ceria he separated three new earths, Ceria proper, Lanthana, and Didymia. Yttria was shown to be a mixture of at least three oxides, for which the names Yttria, Erbia, and Terbia were proposed. These oxides were believed to have the general formula RO, by analogy with the alkaline earths, which they were found to resemble in many respects, notably in their strongly basic character. The properties of the new oxides were examined during the next twenty years by many chemists, the chief workers being Marignac, Rammelsberg, and Hermann, but the next important advance was the investigation of the absorption spectra of solutions of the rare earth salts, first suggested by Gladstone in 1856, and developed more fully by Bunsen and Kirchhoff in 1860 and the following few years. The introduction of the methods of spectrum analysis furnished a very delicate and valuable method of examining and identifying the various oxides, and so greatly assisted the laborious processes of separation. Sixteen elements (excluding thorium and zirconium) are at the present time recognised as belonging to the rare earth group. With one or two exceptions, these show the closest resemblance to one another, both in chemical behaviour and in the properties of their compounds, so that the difficulties of separating and purifying them are very great. They may be said to form a series, in which the properties vary continuously but gradually from member to member, so that no sharp differences are anywhere perceptible. The method of division into groups is, therefore, almost entirely one of convenience, and has arisen from the course which the separations have followed.