The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The elements are divided into two chief families or groups, that of the
cerium metals and that of the yttrium metals respectively. The cerium
elements are separated by a process depending on the relative
insolubility of their alkali double sulphates; in this group are
included cerium, lanthanum, praseodymium, neodymium, and samarium. The
yttrium family is further divided into four sub-groups: the first
consists of scandium and yttrium; the second or terbium group of
europium, gadolinium, and terbium; the third or erbium group of
dysprosium, holmium, erbium, and thulium; and the fourth or ytterbium
group of ytterbium and lutecium--the element celtium, recently
discovered by Urbain, will also fall into this sub-group, but the
discovery awaits confirmation. Whilst scandium and yttrium fall into
somewhat abnormal positions, corresponding to their low atomic weights,
the terbium elements occupy an intermediate position between the cerium
elements and the remaining yttrium elements, or yttrium group proper,
and so are frequently classified as a third or intermediate group.
This list does not include all the names which have been put forward to
designate what have been claimed from time to time as new elements;
whilst the individuality of some of those included is not yet fully
established, and the homogeneity of others has been called in question.
The uncertainty is more pronounced among the yttrium elements than among
the cerium elements; owing to the opportunities for investigation
furnished by the commercial treatment of monazite, the chemistry of the
cerium group may be regarded as complete.
In the following table the elements are arranged in order of increasing
atomic weight, and it can be seen at once how closely the division into
groups follows this order:
ELEMENT ATOMIC WT. COLOUR OF SALTS
{Scandium, Sc 44·1 Colourless
{Yttrium, Yt 89·0 Colourless
{Lanthanum, La 139·0 Colourless
{Cerium, Ce 140·25 Cerous, colourless; ceric,
Cerium { orange to red
Group. {Praseodymium, Pr 140·6 Green
{Neodymium, Nd 144·3 Red to reddish-violet
{Samarium, Sa 150·4 Topaz yellow
Terbium {Europium, Eu 152·0 Faint rose
Group. {Gadolinium, Gd 157·3 Colourless
{Terbium, Tb 159·2 Colourless
{Dysprosium, Dy 162·5 Bright green
Erbium {Holmium, Ho 163·5 Yellow to orange
Group. {Erbium, Er 167·7 Deep rose
{Thulium, Tm 168·5 Bluish-green
Ytterbium {Ytterbium, Yb 172·0 Colourless
Group. {Lutecium, Lu 174·0 Colourless
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