The reaction between manganese dioxide and potassium permanganateHopkins, Arthur John
Science
The reaction between manganese dioxide and potassium permanganate
Hopkins, Arthur John
Manganese; Thesis (Ph. D.)
[10] Decolorized before time was taken.
The results appearing in the table on the same horizontal lines are
those of experiments made simultaneously, that is, the flasks in these
experiments were immersed at the same time and in the same water-bath.
These, that is the results appearing on the same horizontal line,
and these only are comparable, since it was found that very slight
differences in the temperature of the bath were of great influence on
the length of time required for the reduction of the permanganate.
It is clear that the rate of the reduction of the permanganate is
greatly increased by increasing the quantity of the manganese oxide.
After reduction of the permanganate, the contents of the flasks were
in every case filtered and the filtrate tested by Crum’s reaction
for the presence of manganese. No manganese was found. The absence of
manganese in the filtrate shows that the reduction of the permanganate
was not due to the formation of manganese nitrate, though it will be
clear from the results of subsequent experiments that the presence of
nitric acid exerts an influence on the rate of the reduction.
B. In neutral solution.
The condition were the same as under A, except that the nitric acid was
omitted. Those flasks containing potassium permanganate and one, two
and seven molecular equivalents respectively of the manganese oxide
were immersed in the water-bath as before.
No. I {containing one molecule of oxide and
{one molecule KMnO₄ was reduced in 57 hours
No. II {containing two molecules of oxide and
{one molecule KMnO₄ was reduced in
35 hours
No. III {containing seven molecules of oxide
{and one molecule KMnO₄ was reduced in
2¾ hours
C. In alkaline solution.
The conditions were the same as under B, except that five molecules of
potassium hydroxide were added for each molecule of the permanganate.
No. I {containing one molecules of oxide for
{each molecule KMnO₄ was reduced in
91¾ hours.
No. II {containing two molecules of oxide
{for each molecule KMnO₄ was reduced in
55(?) hours.
No. III {containing seven molecules of oxide for
{each molecule KMnO₄ was reduced in
10 hours.
It appears that potassium permanganate is less easily reduced by
manganese oxide in neutral than in acid solutions and in alkaline that
in neutral solutions.
The Reduction of Neutral Potassium Permanganate by Manganese Oxide at
Ordinary Temperature.
In these experiments, the manganese oxide used was prepared in the same
manner as that in which the proportion of manganese to available oxygen
was found immediately after its preparation to be
1.018 : 1.000
Public-domain text, read in full here on John Shaqi.
The reaction between manganese dioxide and potassium permanganate — John Shaqi
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