The reaction between manganese dioxide and potassium permanganateHopkins, Arthur John
Science
The reaction between manganese dioxide and potassium permanganate
Hopkins, Arthur John
Manganese; Thesis (Ph. D.)
The conclusions to be drawn from the foregoing results are (1) that
dilute solutions of potassium permanganate are more stable both in
diffused light and in darkness than the more concentrated ones, and (2)
that the presence of manganese oxides hasten to an enormous degree the
reduction of potassium permanganate even at summer temperatures. It
will also be observed that this reducing action of the manganese oxide
is greater in the stronger than in the more dilute solutions. It should
be remarked that the summer of 1892 in which these experiments were
made, was one of unusual heat.
Action of Potassium Permanganate upon a Manganese Oxide Derived from
Manganese Dioxide by Spontaneous Decomposition.
The oxide used in these experiments was one which had been prepared
in the manner heretofore described by adding manganese sulphate to an
excess of potassium permanganate. Soon after its preparation the ratio
of manganese to available oxygen in it was found to be
1.018 : 1.000
At the time when it was used in these experiments, the ratio of
manganese to available oxygen was found to be
1.198 : 1.000
Corresponding very nearly to the ratio of manganese to available oxygen
in MnO·5MnO₂.
Experiment I.
230 m.g. of the oxide was treated with the quantity of permanganate
calculated to be necessary for its oxidation to manganese dioxide.
The mixture was kept at a temperature of 22°C. until the color of the
permanganate disappeared. This required about ten hours.
An analysis of the oxide then gave a ratio of manganese to available
oxygen
1.027 : 1.000
Experiment II
A repetition of experiment I. An analysis of the oxide after
decolorization of the permanganate gave a ratio of manganese to
available oxygen of
1.022 : 1.000
Experiment III
The conditions are the same as in the preceding experiments except that
twice the amount of permanganate calculated for the conversion of the
oxide into manganese dioxide was added.
An analysis of the residue after decolorization gave a ratio of
manganese to available oxygen of
0.994 : 1.000
Experiment IV
A repetition of experiment III. An analysis of the residue gave a
ratio of manganese to available oxygen of
0.995 : 1.000
Experiment V
A repetition of experiments III and IV. The ratio of manganese to
available oxygen in the residue was
0.995 : 1.000.
The foregoing results indicate (experiments III, IV, and V) that the
oxygen lost spontaneously by manganese dioxide prepared in the wet way,
is fully recovered when the reduced oxide is treated with excess of
potassium permanganate.
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