The Romance of War Inventions: A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed — John Shaqi
The Romance of War Inventions: A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are EmployedCorbin, Thomas W.
History
The Romance of War Inventions: A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed
Corbin, Thomas W.
Inventions; Military art and science; Naval art and science
We cannot obtain the other product, the caustic soda, by the same simple
means. In our little experiment we succeeded in manufacturing some of it
in the region around the cathode, and had we drawn off some of the
liquid from there we would have been able to detect its presence. But it
would have been mixed up with much ordinary salt, and for commercial
purposes we need the caustic soda separate from the salt. The principle
is, however, just the same, as you will see.
Imagine a large oblong vat divided by vertical partitions into three
separate chambers. These partitions do not quite reach the bottom of
the vessel, so that there is a means of communication between all three
chambers. This is closed, however, by filling the lower part of the vat
with mercury up to a level a little higher than the lower ends of the
partitions.
Thus we have three separate chambers with communication between them but
that communication is sealed up by the mercury.
The two end chambers are filled with salt water, or brine, while the
centre one is filled with a solution of caustic soda. In each end
compartment is a stick of graphite, both being electrically joined
together and so connected up that they form anodes, while in the centre
compartment is the cathode.
When the current flows from the anodes it carries the sodium ions with
it, just as it did in our little experiment. But its course, this time,
is not straight, since in order to travel from anode to cathode it has
to pass through the openings in the partitions, in other words through
the mercury.
On arrival at or near the cathode the ions of sodium cause the caustic
soda to be formed just as in our experiment, but in this case, you will
notice, the formation takes place in a chamber from which the salt brine
is completely excluded by the mercury.
Brine is continually fed into the outer chambers and the solution of
caustic soda is drawn from the centre one, while the chlorine is
collected over the anodes.
And now we can go a step further on our progress from common salt to
explosive.
In the soap works there are enormous coppers in which are boiled various
kinds of fat. The source of the fat may be either animal or vegetable,
many kinds of beans, nuts and seeds furnishing fats practically
identical with that which can be got from the fat flesh of a sheep, for
instance. To this fat is added some caustic soda solution and the whole
is kept boiling for some considerable time. This protracted boiling is
to enable the soda thoroughly to attack the fat and combine with it,
whereby two entirely new substances are formed.
Public-domain text, read in full here on John Shaqi.
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