The Romance of War Inventions: A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are EmployedCorbin, Thomas W.
History
The Romance of War Inventions: A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed
Corbin, Thomas W.
Inventions; Military art and science; Naval art and science
We see from this that to make an explosion we require fuel, just as we
do to make a fire: but we need that it shall be very intimately mixed
with oxygen, so that all of it can burn up in practically a single
instant. Now in gunpowder we get these conditions fulfilled. We have the
carbon in the shape of charcoal, we also have some sulphur which
likewise burns readily, and we have saltpetre which contains oxygen.
Thus, you see, we do not need to go to the air for the oxygen, for the
gunpowder possesses it already, locked up in the saltpetre. Moreover, we
can see now why it is so important for all the materials to be ground up
very fine, for it is only by so doing that we can ensure that every
particle of charcoal or sulphur shall have particles of saltpetre close
by ready to furnish oxygen at a moment's notice.
Another thing to be observed, for it lets us into the great key to the
manufacture of nearly all explosives, is the scientific name of
saltpetre. It is "nitrate of potassium," and all substances whose names
begin with "nitr-" contain nitrogen: while the termination "ate"
signifies the presence of oxygen. We need the oxygen to make the
explosion but we do not need the nitrogen, yet the latter has to be
present for without it the oxygen would be too slow in getting to work.
Nitrogen is one of the strangest substances on earth. Extremely lazy
itself, it has the knack of hustling its companions, particularly
oxygen, and making them work with tremendous fury. Whenever we get the
lazy gas nitrogen to enter into a combination with other things we may
confidently look for extraordinary activity of some sort.
So when we put a light to a quantity of gunpowder we set up those
conditions under which the carbon and oxygen can combine, and at the
same moment our lazy friend the nitrogen turns out his partner oxygen
from the nitrate in which they were till then combined and a sudden
burning is the result. The solid gunpowder is suddenly changed into a
volume of hot gas 2500 times as great. That is to say, one cubic inch of
gunpowder changes suddenly into 2500 cubic inches of gas. That sudden
expansion to 2500 times its volume is what we term an explosion. If it
takes place in an enclosed space so that the gas formed wants to expand
but cannot, the result is a pressure of about forty tons per square
inch.
If that enclosed space were the interior of a gun, that force of forty
tons per square inch would be available for driving out the projectile.
Now, gunpowder is still used for sporting purposes and also for some
special purposes in warfare, but it has the great disadvantage that it
makes a lot of smoke, so that the enemy would be easily able to locate
the guns were it to be used in them. As we know so well, by the messages
from France, guns and rifles drop their shells and bullets apparently
from nowhere and are extremely difficult to locate. That is owing to the
use of improved powders one of the great features of which is their
smokelessness.
Public-domain text, read in full here on John Shaqi.
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