The Royal Institution: Its Founder and First ProfessorsJones, Bence
History
The Royal Institution: Its Founder and First Professors
Jones, Bence
Davy, Humphry, Sir, 1778-1829; Royal Institution of Great Britain; Rumford, Benjamin, Graf von, 1753-1814; Young, Thomas, 1773-1829
‘_Remarkable Phenomena with Potash._ It soon--’ Here the laboratory
note ends, but his paper in the ‘Philosophical Transactions’
says--‘fused, became a conductor, and gave brilliant light with
the appearance of flame at the negative wire. When it was slightly
moistened, to make it a better conductor, the potash began to fuse
at both its points of electrisation; there was a violent effusion at
its upper or positive surface, while at the lower or negative surface
there was no liberation of an elastic fluid, but a formation of
small granules resembling quicksilver, which occasionally burst with
explosion.’
He then tried carbonate of ammonia, sulphuric acid and water, soap, and
the flame of a candle.
The following day carbonate of ammonia and oxalic acid were tried,
sulphuric acid, water, and alcohol.
From the 7th to the 16th no experiments were entered in the Laboratory
Book; but to the substance that produced the gas and globules he
gave the name first of alkaligen; for on the 16th he says, ‘Gas from
alkaligen in alcohol;’ also ‘gas from ether and gas from oil of
turpentine.’
On the 17th he again experimented on this gas from the alkaligen in
ether and turpentine, and says, ‘The gas which had been collected from
the globules under oil of turpentine by the action of water burnt in
contact with the air. Does it (the matter of the globules) not form
gaseous compounds with ether, alcohol, and the oils?’
Then he notes the action of the alkaligen on mercury. ‘Forms with it
a solid amalgam, which soon loses its alkaligen in the air.’ ‘This
amalgam amalgamates with platina and iron, but soon flies off on
exposure to the air.’ ‘Query, Does it amalgamate with phosphorus?’
‘Probably whenever it meets with hydrogen it dissolves in it.’
‘Probably forms an æriform compound with ether.’
[Illustration]
On October 19 he made his famous experiment by which he showed
beyond question that potash can give up its oxygen. ‘When potash
was introduced into a tube having a platina wire attached to it, so
(fig.), and fused into the tube so as to be a conductor--_i.e._ so as
to contain just water enough, though solid--and inserted over mercury,
when the platina was made negative, no gas was formed and the mercury
became oxydated, and a small quantity of the alkaligen was produced
round the platina wire, as was evident from its quick inflammation by
the action of water. When the mercury was made the negative, gas was
developed in great quantities from the positive wire, and none from
the negative mercury, and this gas proved to be pure oxygen--a capital
experiment, proving the decomposition of potash.’ ‘A small quantity of
alkaligen was produced round the platina wire.’
‘The gas produced from alkaligen confined under mercury by the contact
of water seemed to be hydrogen nearly pure. Soda decomposed with
different phenomena.’
Davy made no more notes on that day.
Public-domain text, read in full here on John Shaqi.
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