The Science of BrickmakingHarris, George Frederick
Science
The Science of Brickmaking
Harris, George Frederick
Brickmaking -- Handbooks, manuals, etc.
The operator may test his skill by making the following brilliant
experiments. Take up a few small fragments of the mineral malachite (a
carbonate of copper) by means of the clear, colourless, heated borax
bead, and then introduce them to the _oxidising_ flame. They slowly
dissolve in the borax, and, whilst doing so, the tip of the blowpipe
flame becomes emerald-green in colour. After applying this flame for a
minute or two, the whole of the mineral will have become incorporated
with the borax, and, when the bead is still hot, note that it is also
of a rich green tint, but that, on cooling, it turns blue. If too much
malachite has been taken up in the first instance, a very dark green
tint is imparted, which still remains when the bead is cold, and it
appears to be quite black. Its true colour, however, may be ascertained
by flattening the bead out before it is quite cold. It is always well
to begin by using a small quantity of the mineral substance at first,
and adding to this as may be required.
Assuming that a fine rich green bead has been produced, and that it
contains a relatively large amount of copper, the operator may now
hold it in the _reducing_ flame and re-melt the bead; if the operation
has been conducted carefully, the bead will then show red, and be
practically opaque when cold. The red bead may now be re-heated in the
_oxidising_ flame, when it will be found once more to return to a green
colour. The student will find this easy operation excellent practice,
as proving to him, in the absence of a demonstrator, that he is really
able to recognise and use the oxidising and reducing flames at will.
Many mineral substances yield a distinctive colour in this way--a
useful factor in a qualitative analysis.
Before using the platinum wire, be careful to ascertain that it is
quite clean; a borax bead made thereon should be perfectly white and
transparent.
The “platinum foil” is employed as a support during fusions; pieces
about an inch and a half long, by half an inch in width, are generally
used. A small platinum spoon is sometimes adopted when fusing
substances with acid, potassium, sulphate, or nitre.
Minerals may be tested to see whether, in the ordinary blowpipe flame,
they are fusible or not. To do this, a fragment of the substance to be
tested is held in the flame by means of the “platinum-pointed forceps.”
If the mineral is found to be fusible, then its “degree of fusibility”
may be ascertained according to the following table. The “degrees of
fusibility” are six in number:--
1. Fusible in ordinary gasflame, even in large fragments. Example:
_Stibnite_, or grey antimony.
2. Fusible in fine, thin pieces, in the ordinary gasflame, and in
larger fragments in the blowpipe-flame. Example: _Natrolite_, a
hydrous silicate of alumina and soda.
3. If very thin splinters be used, fusible without difficulty with
the blowpipe-flame. Example: _Almandite_, or iron-alumina-garnet.
Public-domain text, read in full here on John Shaqi.
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