The Science of BrickmakingHarris, George Frederick
Science
The Science of Brickmaking
Harris, George Frederick
Brickmaking -- Handbooks, manuals, etc.
Sulphuric acid is found in the air of large cities principally as
a product of combustion, and is, of course, a distinct impurity. A
portion of this acid is free, and a larger quantity is combined. Free
sulphuric acid is very destructive to clay goods in the open; and it
should be remembered that the relative abundance of this impurity
depends on the precise _locale_ in the city. A great deal has been said
and written about the decomposition of the stone of which the Houses of
Parliament are built. The air in the immediate vicinity must be highly
charged with both sulphuric and nitric acid from the proximity of the
busy factories on the opposite banks of the Thames in Lambeth. Had the
Houses of Parliament been erected, say, in Kensington, where but few
factories exist, it is conceivable that the stone would have behaved
much better.
Air in itself, however, has no power to destroy bricks--the various
gases, acids, chlorides, salts, solid carbon, inorganic and organic
dust can do nothing by themselves. But the air is always laden with
vapour, the most important of which is water vapour, which condenses
into rain, hail, snow, and dew. When rain is formed, the drops of water
take up minute quantities of air with its proportion of carbonic acid,
sulphuric acid, or what not, and it is these acids, applied to the
surface of bricks through the medium of rain and moisture generally,
that are liable to do the damage if the nature and composition of the
brick are favourable.
Let us assume that we have a brick composed of a goodly percentage of
carbonate of lime. The carbonic acid in the rain reduces this to a
bi-carbonate, which is soluble in water, and hence the surface of the
brick decays, the rain water washing it away. Other things being equal,
it follows that the same brick will decay most rapidly in a district
where the rainfall is very great and where there is the largest
proportion of these deleterious acids in the air.
Public-domain text, read in full here on John Shaqi.
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