The Story of a Piece of Coal: What It Is, Whence It Comes, and Whither It GoesMartin, Edward A. (Edward Alfred)
Science
The Story of a Piece of Coal: What It Is, Whence It Comes, and Whither It Goes
Martin, Edward A. (Edward Alfred)
Coal
Aniline has been previously referred (p. 135) to as having been prepared
from nitro-benzole, or _essence de mirbane_, and its preparation, by
treating this substance with iron-filings and acetic acid, was one of the
early triumphs of the chemists who undertook the search after the unknown
contained in gas-tar. It had previously been obtained from oils distilled
from bones. The importance of the substance lies in the fact that, by the
action of various chemical reagents, a series of colouring matters of
very great richness are formed, and these are the well-known _aniline
dyes_.
As early as 1836, it was discovered that aniline, when heated with
chloride of lime, acquired a beautiful blue tint. This discovery led to
no immediate practical result, and it was not until twenty-one years
after that a further discovery was made, which may indeed be said to have
achieved a world-wide reputation. It was found that, by adding bichromate
of potash to a solution of aniline and sulphuric acid, a powder was
obtained from which the dye was afterwards extracted, which is known as
_mauve_. Since that time dyes in all shades and colours have been
obtained from the same source. _Magenta_ was the next dye to make its
appearance, and in the fickle history of fashion, probably no colours
have had such extraordinary runs of popularity as those of mauve and
magenta. Every conceivable colour was obtained in due course from the
same source, and chemists began to suspect that, in the course of time,
the colouring matter of dyer's madder, which was known as _alizarin_,
would also be obtained therefrom. Hitherto this had been obtained from
the root of the madder-plant, but by dint of careful and well-reasoned
research, it was obtained by Dr Groebe, from a solid crystalline coal-tar
product, known as _anthracene_, (C_{12}H_{14}). This artificial alizarin
yields colours which are purer than those of natural madder, and being
derived from what was originally regarded as a waste product, its cost of
production is considerably cheaper.
We have endeavoured thus far to deal with (1) gas, and (2) tar, the two
principal products in the distillation of coal. We have yet to say a few
words concerning the useful ammoniacal liquor, and the final residue in
the retorts, _i.e._, coke.
Public-domain text, read in full here on John Shaqi.
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