The Story of a Piece of Coal: What It Is, Whence It Comes, and Whither It GoesMartin, Edward A. (Edward Alfred)
Science
The Story of a Piece of Coal: What It Is, Whence It Comes, and Whither It Goes
Martin, Edward A. (Edward Alfred)
Coal
The ammoniacal liquor which has been passing over during distillation of
the coal, and which has been collecting in the hydraulic main and in
other parts of the gas-making apparatus, is set aside to be treated to a
variety of chemical reactions, in order to wrench from it its useful
constituents. Amongst these, of course, _ammonia_ stands in the first
rank, the others being comparatively unimportant. In order to obtain
this, the liquor is first of all neutralised by being treated with a
quantity of acid, which converts the principal constituent of the liquor,
viz., carbonate of ammonia (smelling salts), into either sulphate of
ammonia, or chloride of ammonia, familiarly known as sal-ammoniac,
according as sulphuric acid or hydrochloric acid is the acid used. Thus
carbonate of ammonia with sulphuric acid will give sulphate of ammonia,
but carbonate of ammonia with hydrochloric acid will give sal-ammoniac
(chloride of ammonia). By a further treatment of these with lime, or, as
it is chemically known, oxide of calcium, ammonia is set free, whilst
chloride of lime (the well-known disinfectant), or sulphate of lime
(gypsum, or "plaster of Paris" ), is the result.
Thus:
Sulphate of ammonia + lime = plaster of Paris + ammonia.
or,
Sal-ammoniac + lime = chloride of lime + ammonia.
Ammonia itself is a most powerful gas, and acts rapidly upon the eyes. It
has a stimulating effect upon the nerves. It is not a chemical element,
being composed of three parts of hydrogen by weight to one of nitrogen,
both of which elements alone are very harmless, and, the latter indeed,
very necessary to human life. Ammonia is fatal to life, producing great
irritation of the lungs.
It has also been called "hartshorn," being obtained by destructive
distillation of horn and bone. The name "ammonia" is said to have been
derived from the fact that it was first obtained by the Arabs near the
temple of Jupiter Ammon, in Lybia, North Africa, from the excrement of
camels, in the form of sal-ammoniac. There are always traces of it in the
atmosphere, especially in the vicinity of large towns and manufactories
where large quantities of coal are burned.
Coke, if properly prepared, should consist of pure carbon. Good coal
should yield as much as 80 per cent. of coke, but owing to the
unsatisfactory manner of its production, this proportion is seldom
yielded, whilst the coke which is familiar to householders, being the
residue left in the retorts after gas-making, usually contains so large a
proportion of sulphur as to make its combustion almost offensive. No
doubt the result of its unsatisfactory preparation has been that it has
failed to make its way into households as it should have done, but there
is also another objection to its use, namely, the fact that, owing to the
quantity of oxygen required in its combustion, it gives rise to feelings
of suffocation where insufficient ventilation of the room is provided.
Public-domain text, read in full here on John Shaqi.
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