The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
That he might bring into one point of view, and compare the various
changes effected by the agency of fire, Stahl invented a new
Principle, which he named _Phlogiston_, and constructed an hypothesis
which is generally known as the phlogistic theory. He explained, and
applied, this hypothesis in various books, especially in one published
at Halle in 1717.
Stahl observed that many substances which differed much from one
another in various respects were alike in one respect; they were all
combustible. All the combustible substances, he argued, must contain a
common principle; he named this supposed principle, _phlogiston_ (from
the Greek word _phlogistos_ = burnt, or set on fire). Stahl said that
the phlogiston of a combustible thing escapes as the substance burns,
and, becoming apparent to the senses, is named fire or flame. The
phlogiston in a combustible substance was supposed to be so
intimately associated with something else that our senses cannot
perceive it; nevertheless, the theory said, it is there; we can see
only the escaping phlogiston, we can perceive only the phlogiston
which is set free from its combination with other things. The theory
thought of phlogiston as imprisoned in the thing which can be burnt,
and as itself forming part of the prison; that the prisoner should be
set free, the walls of the prison had to be removed; the freeing of
the prisoner destroyed the prison. As escaping, or free, phlogiston
was called fire, or flame, so the phlogiston in a combustible
substance was sometimes called combined fire, or flame in the state of
combination. A peculiarity of the strange thing called phlogiston was
that it preferred to be concealed in something, hidden, imprisoned,
combined; free phlogiston* was supposed to be always ready to become
combined phlogiston.
*Transcriber's Note: Original "phlogstion".
The phlogistic theory said that what remains when a substance has been
burnt is the original substance deprived of phlogiston; and,
therefore, to restore the phlogiston to the product of burning is to
re-form the combustible substance. But how is such a restoration of
phlogiston to be accomplished? Evidently by heating the burnt thing
with something which is very ready to burn. Because, according to the
theory, everything which can be burnt contains phlogiston, the more
ready a substance is to burn the richer it is in phlogiston; burning
is the outrush of phlogiston, phlogiston prefers to be combined with
something; therefore, if you mix what remains after burning, with
something which is very combustible, and heat the mixture, you are
bringing the burnt matter under conditions which are very favourable
for the reception of phlogiston by it, for you are bringing it into
intimate contact with something from which freedom-hating phlogiston
is being forced to escape.
Public-domain text, read in full here on John Shaqi.
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