The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
Charcoal, sulphur, phosphorus, oils and fats are easily burnt; these
substances were, therefore, chosen for the purpose of changing things
which had been burnt into things which could again be burnt; these,
and a few other substances like these, were classed together, and
called _phlogisticating agents_.
Very many of the substances which were dealt with by the experimenters
of the last quarter of the 17th, and the first half of the 18th,
century, were either substances which could be burned, or those which
had been produced by burning; hence the phlogistic theory brought into
one point of view, compared, and emphasised the similarities between,
a great many things which had not been thought of as connected before
that theory was promulgated. Moreover, the theory asserted that all
combustible, or incinerable, things are composed of phlogiston, and
another principle, or, as was often said, another element, which is
different in different kinds of combustible substances. The metals,
for instance, were said to be composed of phlogiston and an earthy
principle or element, which was somewhat different in different
metals. The phlogisteans taught that the earthy principle of a metal
remains in the form of ash, cinders, or calx, when the metal is
calcined, or, as they expressed it, when the metal is deprived of its
phlogiston.
The phlogistic theory savoured of alchemy; it postulated an undefined,
undefinable, intangible Principle; it said that all combustible
substances are formed by the union of this Principle with another,
which is sometimes of an earthy character, sometimes of a fatty
nature, sometimes highly volatile in habit. Nevertheless, the theory
of Stahl was a step away from purely alchemical conceptions towards
the accurate description of a very important class of changes. The
principle of phlogiston could be recognised by the senses as it was in
the act of escaping from a substance; and the other principle of
combustible things was scarcely a Principle in the alchemical sense,
for, in the case of metals at any rate, it remained when the things
which had contained it were burnt, and could be seen, handled, and
weighed. To say that metals are composed of phlogiston and an earthy
substance, was to express facts in such a language that the expression
might be made the basis of experimental inquiry; it was very different
from the assertion that metals are produced by the spiritual actions
of the three Principles, salt, mercury and sulphur, the first of which
is not salt, the second is not mercury, and the third is not sulphur.
The followers of Stahl often spoke of metals as composed of phlogiston
and an _element_ of an earthy character; this expression also was an
advance, from the hazy notion of _Element_ in purely alchemical
writings, towards accuracy and fulness of description. An element was
now something which could he seen and experimented with; it was no
longer a semi-spiritual existence which could not be grasped by the
senses.
Public-domain text, read in full here on John Shaqi.
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