The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
The phlogistic theory regarded the calcination of a metal as the
separation of it into two things, unlike the metal, and unlike each
other; one of these things was phlogiston, the other was an earth-like
residue. The theory thought of the re-formation of a metal from its
calx, that is, the earthy substance which remains after combustion, as
the combination of two things to produce one, apparently homogeneous,
substance. Metals appeared to the phlogisteans, as they appeared to
the alchemists, to be composite substances. Processes of burning were
regarded by alchemists and phlogisteans alike, as processes of
simplification.
The fact had been noticed and recorded, during the middle ages, that
the earth-like matter which remains when a metal is calcined is
heavier than the metal itself. From this fact, modern investigators of
natural phenomena would draw the conclusion, that calcination of a
metal is an addition of something to the metal, not a separation of
the metal into different things. It seems impossible to us that a
substance should be separated into portions, and one of these parts
should weigh as much as, or more than, the whole.
The exact investigation of material changes called chemistry rests on
the statement that _mass_, and mass is practically measured by
_weight_, is the one property of what we call matter, the
determination whereof enables us to decide whether a change is a
combination, or coalescence, of different things, or a separation of
one thing into parts. That any part of a material system can be
removed without the weight of the portion which remains being less
than the original weight of the whole system, is unthinkable, in the
present state of our knowledge of material changes.
But in the 17th century, and throughout most of the 18th, only a few
of those who examined changes in the properties of substances paid
heed to changes of weight; they had not realised the importance of the
property of mass, as measured by weight. The convinced upholder of the
phlogistic theory had two answers to the argument, that, because the
earth-like product of the calcination of a metal weighs more than the
metal itself, therefore the metal cannot have lost something in the
process; for, if one portion of what is taken away weighs more than
the metal from which it has been separated, it is evident that the
weight of the two portions into which the metal is said to have been
divided must be considerably greater than the weight of the undivided
metal. The upholders of the theory sometimes met the argument by
saying, "Of course the calx weighs more than the metal, because
phlogiston tends to lighten a body which contains it; and therefore
the body weighs more after it has lost phlogiston than it did when the
phlogiston formed part of it;" sometimes, and more often, their answer
was--"loss or gain of weight is an accident, the essential thing is
change of qualities."
Public-domain text, read in full here on John Shaqi.
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