The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
In Chapter VI., I said that when an alchemist boiled water in an open
vessel, and obtained a white earthy solid, in place of the water which
disappeared, he was producing some sort of experimental proof of the
justness of his assertion that water can be changed into earth.
Lavoisier began his work on the transformations of matter by
demonstrating that this alleged transmutation does not happen; and he
did this by weighing the water, the vessel, and the earthy solid.
Lavoisier had constructed for him a pelican of white glass (see Fig.
XI., p. 88), with a stopper of glass. He cleaned, dried, and weighed
this vessel; then he put into it rain-water which he had distilled
eight times; he heated the vessel, removing the stopper from time to
time to allow the expanding air to escape, then put in the stopper,
allowed the vessel to cool, and weighed very carefully. The difference
between the second and the first weighing was the weight of water in
the vessel. He then fastened the stopper securely with cement, and
kept the apparatus at a temperature about 30° or 40° below that of
boiling water, for a hundred and one days. At the end of that time a
fine white solid had collected on the bottom of the vessel. Lavoisier
removed the cement from the stopper, and weighed the apparatus; the
weight was the same as it had been before the heating began. He
removed the stopper; air rushed in, with a hissing noise. Lavoisier
concluded that air had not penetrated through the apparatus during the
process of heating. He then poured out the water, and the solid which
had formed in the vessel, set them aside, dried, and weighed the
pelican; it had lost 17-4/10 grains. Lavoisier concluded that the
solid which had formed in the water was produced by the solvent action
of the water on the glass vessel. He argued that if this conclusion
was correct, the weight of the solid must be equal to the loss of
weight suffered by the vessel; he therefore separated the solid from
the water in which it was suspended, dried, and weighed it. The solid
weighed 4-9/10 grains. Lavoisier's conclusion seemed to be incorrect;
the weight of the solid, which was supposed to be produced by the
action of the water on the vessel, was 12-1/2 grains less than the weight
of the material removed from the vessel. But some of the material
which was removed from the vessel might have remained dissolved in the
water: Lavoisier distilled the water, which he had separated from the
solid, in a glass vessel, until only a very little remained in the
distilling apparatus; he poured this small quantity into a glass
basin, and boiled until the whole of the water had disappeared as
steam. There remained a white, earthy solid, the weight of which was
15-1/2 grains. Lavoisier had obtained 4-9/10 + 15-1/2 = 20-2/5 grains
of solid; the pelican had lost 17-2/5 grains. The difference between
these weights, namely, 3 grains, was accounted for by Lavoisier as due
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