The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
to the solvent action of the water on the glass apparatus wherein it
had been distilled, and on the glass basin wherein it had been
evaporated to dryness.
Lavoisier's experiments proved that when distilled water is heated in
a glass vessel, it dissolves some of the material of the vessel, and
the white, earthy solid which is obtained by boiling down the water is
merely the material which has been removed from the glass vessel. His
experiments also proved that the water does not undergo any change
during the process; that at the end of the operation it is what it was
at the beginning--water, and nothing but water.
By this investigation Lavoisier destroyed part of the experimental
basis of alchemy, and established the one and only method by which
chemical changes can be investigated; the method wherein constant use
is made of the balance.
Lavoisier now turned his attention to the calcination of metals, and
particularly the calcination of tin. Boyle supposed that the increase
in weight which accompanies the calcination of a metal is due to the
fixation of "matter of fire" by the calcining metal; Rey regarded the
increase in weight as the result of the combination of the air with
the metal; Mayow thought that the atmosphere contains two different
kinds of "airs," and one of these unites with the heated metal.
Lavoisier proposed to test these suppositions by calcining a weighed
quantity of tin in a closed glass vessel, which had been weighed
before, and should be weighed after, the calcination. If Boyle's view
was correct, the weight of the vessel and the tin would be greater at
the end than it was at the beginning of the operation; for "matter of
fire" would pass through the vessel and unite with the metal. If there
was no change in the total weight of the apparatus and its contents,
and if air rushed in when the vessel was opened after the calcination,
and the total weight was then greater than at the beginning of the
process, it would be necessary to adopt either the supposition of Rey
or that of Mayow.
Lavoisier made a series of experiments. The results were these: there
was no change in the total weight of the apparatus and its contents;
when the vessel was opened after the calcination was finished, air
rushed in, and the whole apparatus now weighed more than it did before
the vessel was opened; the weight of the air which rushed in was
exactly equal to the increase in the weight of the tin produced by the
calcination, in other words, the weight of the inrushing air was
exactly equal to the difference between the weights of the tin and the
calx formed by calcining the tin. Lavoisier concluded that to calcine
tin is to cause it to combine with a portion of the air wherein it is
calcined. The weighings he made showed that about one-fifth of the
whole weight of air in the closed flask wherein he calcined tin had
disappeared during the operation.
Public-domain text, read in full here on John Shaqi.
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